{PPN}{(methyl)tetracarbonyl iron}

Base Information

Chemical Name:{PPN}{(methyl)tetracarbonyl iron}
CAS No.:113669-31-1
Molecular Formula:C₅H₃FeO₄*C₃₆H₃₀NP₂
Molecular Weight:721.512
Hs Code.:

Synonyms:{PPN}{(methyl)tetracarbonyl iron}

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Chemical Property of {PPN}{(methyl)tetracarbonyl iron}

Chemical Property:

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Technology Process of {PPN}{(methyl)tetracarbonyl iron}

There total 3 articles about {PPN}{(methyl)tetracarbonyl iron} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

: 56791-54-9
bis(triphenylphosphine)iminium tetracarbonylhydridoferrate⁽⁰⁾

: 80-48-8
methyl p-toluene sulfonate

: 113669-31-1
{PPN}{(methyl)tetracarbonyl iron}

Guidance literature:: With n-C₄H₉Li; In tetrahydrofuran; Under N2, dissolving of Fe-complex in freshly distd. THF, cooling (-78°C), dropwise addn. of n-BuLi in hexane until the soln. is dark red, warming, cannulation of dark red supernatant, washing, drying in vac., addn. of THF then methyltosylate.; Filtn. of light brown soln. through Celite, slow addn. of ether yields light tan ppt., recrystn. (THF/ether), elem. anal.;

Reference yield:

: 113669-28-6
{PPN}{(methyl)iron(tungsten)(carbonyl)9}

: 14040-11-0
tungsten hexacarbonyl

: 113669-31-1
{PPN}{(methyl)tetracarbonyl iron}

Guidance literature:: With CO; In tetrahydrofuran; Addn. of THF to complex, evacuating and back-filling with CO to 1 atm (room temp., 2 days).; IR spectroscopy.;

Reference yield:

: 99604-07-6
{PPN}2{iron(tungsten)(carbonyl)9}

: 113669-31-1
{PPN}{(methyl)tetracarbonyl iron}

Guidance literature:: Multi-step reaction with 2 steps

1: acetonitrile

2: CO / tetrahydrofuran

With CO; In tetrahydrofuran; acetonitrile;