triisopropyl-[3-(3,4,5-trimethoxy-phenyl)-propoxy]-silane

Base Information

Chemical Name:triisopropyl-[3-(3,4,5-trimethoxy-phenyl)-propoxy]-silane
CAS No.:327025-17-2
Molecular Formula:C₂₁H₃₈O₄Si
Molecular Weight:382.616
Hs Code.:

Synonyms:triisopropyl-[3-(3,4,5-trimethoxy-phenyl)-propoxy]-silane

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Chemical Property of triisopropyl-[3-(3,4,5-trimethoxy-phenyl)-propoxy]-silane

Chemical Property:

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MSDS Files:: SDS file from LookChem

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Technology Process of triisopropyl-[3-(3,4,5-trimethoxy-phenyl)-propoxy]-silane

There total 1 articles about triisopropyl-[3-(3,4,5-trimethoxy-phenyl)-propoxy]-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 53560-26-2
3-(3,4,5-trimethoxyphenyl)propan-1-ol

: 80522-42-5
triisopropylsilyl trifluoromethanesulfonate

: 327025-17-2
triisopropyl-[3-(3,4,5-trimethoxy-phenyl)-propoxy]-silane

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at 20 ℃; for 5h;
DOI:10.1016/S0040-4020(00)00862-0

Reference yield: 95.0%

: 327025-17-2
triisopropyl-[3-(3,4,5-trimethoxy-phenyl)-propoxy]-silane

: 327025-04-7
5-(3-triisopropylsiloxypropyl)-4-iodo-1,2,3-trimethoxybenzene

Guidance literature:: With iodine; silver trifluoroacetate; sodium hydrogencarbonate; In chloroform; at 0 ℃; for 3h;
DOI:10.1016/S0040-4020(00)00862-0

Reference yield:

: 327025-17-2
triisopropyl-[3-(3,4,5-trimethoxy-phenyl)-propoxy]-silane

: 64-86-8,54192-66-4
colchicine

Guidance literature:: Multi-step reaction with 16 steps

1.1: 95 percent / silver trifluoroacetate; I₂; sodium bicarbonate / CHCl₃ / 3 h / 0 °C

2.1: 92 percent / Et₂NH; bis[triphenylphosphine]palladium dichloride; copper(I) iodide / dimethylsulfoxide / 20 h / 90 °C

3.1: 98 percent / n-Bu₄NF / tetrahydrofuran / 7 h / 20 °C

4.1: 96 percent / oxalyl chloride; DMSO / CH₂Cl₂ / 0.75 h / -78 °C

5.1: BH₃*THF / tetrahydrofuran / 1 h / 20 °C

5.2: t-BuLi / pentane; tetrahydrofuran / 0.67 h / -78 °C

5.3: 64 percent / tetrahydrofuran; pentane / 3 h / -78 °C

6.1: 96 percent / oxalyl chloride; DMSO / CH₂Cl₂ / 0.5 h / -78 °C

7.1: 85 percent / BH₃*THF; (S)-(-)-2-amino-3-methyl-1,1-diphenylbutan-1-ol / tetrahydrofuran / 6 h / 23 °C

8.1: 60 percent / diphenylphosphoryl azide; triphenylphosphine; diisopropylazodicarboxylate / tetrahydrofuran / 12 h / 20 °C

9.1: 95 percent / Ph₃P / tetrahydrofuran; H₂O / 50 h / 20 °C

10.1: 98 percent / DMAP; Et₃N / diethyl ether / 7 h / 20 °C

11.1: 60 percent / various solvent(s) / 66 h / Heating

12.1: 99 percent / Et₃N; 4-(dimethylamino)pyridine / CH₂Cl₂ / 10 h / 35 °C

13.1: 99 percent / aq. LiOH / tetrahydrofuran / 12 h

14.1: 45 percent Turnov_. / trimethylsilyltriflate / various solvent(s) / -78 - -60 °C

15.1: 62 percent / Et₃N; trimethylsilyl triflate / CH₂Cl₂ / 2 h / 0 °C

16.1: HCl / diethyl ether / 1 h / 20 °C

16.2: 98 percent / 4-(dimethylamino)pyridine; Et₃N / diethyl ether / 10 h / 25 °C

With hydrogenchloride; dmap; bis-triphenylphosphine-palladium(II) chloride; lithium hydroxide; copper(l) iodide; borane-THF; oxalyl dichloride; trimethylsilyl trifluoromethanesulfonate; di-isopropyl azodicarboxylate; diphenylphosphoranyl azide; tetrabutyl ammonium fluoride; iodine; silver trifluoroacetate; sodium hydrogencarbonate; 1,1-diphenyl-L-valinol; dimethyl sulfoxide; diethylamine; triethylamine; triphenylphosphine; In tetrahydrofuran; diethyl ether; dichloromethane; chloroform; water; dimethyl sulfoxide; 2.1: Sonogashira coupling / 4.1: Swern oxidation / 6.1: Swern oxidation / 11.1: intramolecular Diels-Alder reaction;
DOI:10.1016/S0040-4020(00)00862-0