(Z)-3-(5-((tert-butyldimethylsilyl)oxy)pent-1-en-1-yl)-1-methylcyclohex-2-enol

Base Information

Chemical Name:(Z)-3-(5-((tert-butyldimethylsilyl)oxy)pent-1-en-1-yl)-1-methylcyclohex-2-enol
CAS No.:1424273-64-2
Molecular Formula:C₁₈H₃₄O₂Si
Molecular Weight:310.552
Hs Code.:

Synonyms:(Z)-3-(5-((tert-butyldimethylsilyl)oxy)pent-1-en-1-yl)-1-methylcyclohex-2-enol

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Chemical Property of (Z)-3-(5-((tert-butyldimethylsilyl)oxy)pent-1-en-1-yl)-1-methylcyclohex-2-enol

Chemical Property:

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Technology Process of (Z)-3-(5-((tert-butyldimethylsilyl)oxy)pent-1-en-1-yl)-1-methylcyclohex-2-enol

There total 3 articles about (Z)-3-(5-((tert-butyldimethylsilyl)oxy)pent-1-en-1-yl)-1-methylcyclohex-2-enol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₁₇H₃₀O₂Si

: 917-54-4
methyllithium

: 1424273-63-1
(E)-3-(5-((tert-butyldimethylsilyl)oxy)pent-1-en-1-yl)-1-methylcyclohex-2-enol

: 1424273-64-2
(Z)-3-(5-((tert-butyldimethylsilyl)oxy)pent-1-en-1-yl)-1-methylcyclohex-2-enol

Guidance literature:: C₁₇H₃₀O₂Si; methyllithium; In diethyl ether; at -78 ℃; for 0.333333h; Inert atmosphere;

With water; ammonium chloride; In diethyl ether; Inert atmosphere;
DOI:10.1016/j.tet.2013.01.030

Reference yield:

: 61362-77-4
5-[tert-butyldimethylsilyloxy]pent-1-yne

: 1424273-63-1
(E)-3-(5-((tert-butyldimethylsilyl)oxy)pent-1-en-1-yl)-1-methylcyclohex-2-enol

: 1424273-64-2
(Z)-3-(5-((tert-butyldimethylsilyl)oxy)pent-1-en-1-yl)-1-methylcyclohex-2-enol

Guidance literature:: Multi-step reaction with 3 steps

1.1: 2,2'-azobis(isobutyronitrile) / 0.58 h / 90 °C / Inert atmosphere

2.1: bis-triphenylphosphine-palladium(II) chloride / 4 h / 45 °C / Inert atmosphere

3.1: diethyl ether / 0.33 h / -78 °C / Inert atmosphere

3.2: Inert atmosphere

With bis-triphenylphosphine-palladium(II) chloride; 2,2'-azobis(isobutyronitrile); In diethyl ether;
DOI:10.1016/j.tet.2013.01.030

Reference yield:

: 127020-47-7,127020-48-8
tert-butyldimethyl((5-(tributylstannyl)pent-4-en-1-yl)oxy)silane

: 1424273-63-1
(E)-3-(5-((tert-butyldimethylsilyl)oxy)pent-1-en-1-yl)-1-methylcyclohex-2-enol

: 1424273-64-2
(Z)-3-(5-((tert-butyldimethylsilyl)oxy)pent-1-en-1-yl)-1-methylcyclohex-2-enol

Guidance literature:: Multi-step reaction with 2 steps

1.1: bis-triphenylphosphine-palladium(II) chloride / 4 h / 45 °C / Inert atmosphere

2.1: diethyl ether / 0.33 h / -78 °C / Inert atmosphere

2.2: Inert atmosphere

With bis-triphenylphosphine-palladium(II) chloride; In diethyl ether;
DOI:10.1016/j.tet.2013.01.030