(2E,10E)-diethyl 2,3,10,11-tetradeoxy-4,5,8,9-tetrakis-O-<(1,1-dimethylethyl)dimethylsilyl>-6,7-bis-O-(phenylmethyl)-D-threo-L-galacto-dodeca-2,10-dienarate

Base Information

Chemical Name:(2E,10E)-diethyl 2,3,10,11-tetradeoxy-4,5,8,9-tetrakis-O-<(1,1-dimethylethyl)dimethylsilyl>-6,7-bis-O-(phenylmethyl)-D-threo-L-galacto-dodeca-2,10-dienarate
CAS No.:139631-30-4
Molecular Formula:C₅₄H₉₄O₁₀Si₄
Molecular Weight:1015.68
Hs Code.:

(2E,10E)-diethyl 2,3,10,11-tetradeoxy-4,5,8,9-tetrakis-O-<(1,1-dimethylethyl)dimethylsilyl>-6,7-bis-O-(phenylmethyl)-D-threo-L-galacto-dodeca-2,10-dienarate

Synonyms:(2E,10E)-diethyl 2,3,10,11-tetradeoxy-4,5,8,9-tetrakis-O-<(1,1-dimethylethyl)dimethylsilyl>-6,7-bis-O-(phenylmethyl)-D-threo-L-galacto-dodeca-2,10-dienarate

Suppliers and Price of (2E,10E)-diethyl 2,3,10,11-tetradeoxy-4,5,8,9-tetrakis-O-<(1,1-dimethylethyl)dimethylsilyl>-6,7-bis-O-(phenylmethyl)-D-threo-L-galacto-dodeca-2,10-dienarate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (2E,10E)-diethyl 2,3,10,11-tetradeoxy-4,5,8,9-tetrakis-O-<(1,1-dimethylethyl)dimethylsilyl>-6,7-bis-O-(phenylmethyl)-D-threo-L-galacto-dodeca-2,10-dienarate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (2E,10E)-diethyl 2,3,10,11-tetradeoxy-4,5,8,9-tetrakis-O-<(1,1-dimethylethyl)dimethylsilyl>-6,7-bis-O-(phenylmethyl)-D-threo-L-galacto-dodeca-2,10-dienarate

There total 5 articles about (2E,10E)-diethyl 2,3,10,11-tetradeoxy-4,5,8,9-tetrakis-O-<(1,1-dimethylethyl)dimethylsilyl>-6,7-bis-O-(phenylmethyl)-D-threo-L-galacto-dodeca-2,10-dienarate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 139631-30-4
(2E,10E)-diethyl 2,3,10,11-tetradeoxy-4,5,8,9-tetrakis-O-<(1,1-dimethylethyl)dimethylsilyl>-6,7-bis-O-(phenylmethyl)-D-threo-L-galacto-dodeca-2,10-dienarate

Guidance literature:: Multi-step reaction with 4 steps

1: 100 percent / 2,6-dimethyllutidine / CH₂Cl₂ / 14 h / Ambient temperature

2: 10 percent / DIBAL-H / CH₂Cl₂ / 1 h / -78 °C

3: 1.) oxalyl chloride, DMSO / 1.) dichloromethane, -78 deg C, 10 min, 2.) dichloromethane, 30 min

4: 1.) n-BuLi / 1.) THF, hexane, -78 deg C, 5 min, 2.) THF, hexane, RT, 3 h

With 2,6-dimethyllutidine; n-butyllithium; oxalyl dichloride; diisobutylaluminium hydride; dimethyl sulfoxide; In dichloromethane;

Reference yield:

: 130860-91-2
*,R^*)>-diethyl (2E,6E)-4,5-bis(phenylmethoxy)-2,6-octadienedioate

: 139631-30-4
(2E,10E)-diethyl 2,3,10,11-tetradeoxy-4,5,8,9-tetrakis-O-<(1,1-dimethylethyl)dimethylsilyl>-6,7-bis-O-(phenylmethyl)-D-threo-L-galacto-dodeca-2,10-dienarate

Guidance literature:: Multi-step reaction with 5 steps

1: 71 percent / N-methylmorpholine N-oxide, OsO₄ / acetone; H₂O / 18 h / Ambient temperature

2: 100 percent / 2,6-dimethyllutidine / CH₂Cl₂ / 14 h / Ambient temperature

3: 10 percent / DIBAL-H / CH₂Cl₂ / 1 h / -78 °C

4: 1.) oxalyl chloride, DMSO / 1.) dichloromethane, -78 deg C, 10 min, 2.) dichloromethane, 30 min

5: 1.) n-BuLi / 1.) THF, hexane, -78 deg C, 5 min, 2.) THF, hexane, RT, 3 h

With 2,6-dimethyllutidine; osmium(VIII) oxide; n-butyllithium; oxalyl dichloride; diisobutylaluminium hydride; dimethyl sulfoxide; 4-methylmorpholine N-oxide; In dichloromethane; water; acetone;

Reference yield:

: 130860-92-3
diethyl 2,3,6,7-tetrakis-O-<(1,1-dimethylethyl)dimethylsilyl>-4,5-bis-O-(phenylmethyl)-D-threo-L-galacto-octarate

: 139631-30-4
(2E,10E)-diethyl 2,3,10,11-tetradeoxy-4,5,8,9-tetrakis-O-<(1,1-dimethylethyl)dimethylsilyl>-6,7-bis-O-(phenylmethyl)-D-threo-L-galacto-dodeca-2,10-dienarate

Guidance literature:: Multi-step reaction with 3 steps

1: 10 percent / DIBAL-H / CH₂Cl₂ / 1 h / -78 °C

2: 1.) oxalyl chloride, DMSO / 1.) dichloromethane, -78 deg C, 10 min, 2.) dichloromethane, 30 min

3: 1.) n-BuLi / 1.) THF, hexane, -78 deg C, 5 min, 2.) THF, hexane, RT, 3 h

With n-butyllithium; oxalyl dichloride; diisobutylaluminium hydride; dimethyl sulfoxide; In dichloromethane;