C₅₇H₇₂O₁₀Si

Base Information

Chemical Name:C₅₇H₇₂O₁₀Si
CAS No.:537036-46-7
Molecular Formula:C₅₇H₇₂O₁₀Si
Molecular Weight:945.278
Hs Code.:

C<sub>57</sub>H<sub>72</sub>O<sub>10</sub>Si

Synonyms:C₅₇H₇₂O₁₀Si

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Chemical Property of C₅₇H₇₂O₁₀Si

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Technology Process of C₅₇H₇₂O₁₀Si

There total 29 articles about C₅₇H₇₂O₁₀Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 537036-45-6
3-benzyloxy-2-(2-benzyloxy-ethyl)-11-[3-(tert-butyl-diphenyl-silanyloxymethyl)-3-methyl-2-(toluene-4-sulfonyl)-oxiranylmethyl]-2,10-dimethyl-10-trimethylsilanyloxy-octadecahydro-1,5,7,12,14-pentaoxa-cyclohepta[b]naphthacene

: 537036-46-7
C₅₇H₇₂O₁₀Si

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; at 0 ℃;
DOI:10.1016/S0040-4039(03)00252-1

Reference yield:

: 537036-26-3
(2S,3R,5S,6R)-5-benzyloxy-6-(2-benzyloxyethyl)-2-hydroxymethyl-6-methyltetrahydropyran-3-ol

: 537036-46-7
C₅₇H₇₂O₁₀Si

Guidance literature:: Multi-step reaction with 25 steps

1.1: 2,6-lutidine / CH₂Cl₂ / 0.5 h / -78 °C

1.2: 86 percent / CH₂Cl₂

2.1: 91 percent / n-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide / -100 °C

3.1: 74 percent / TsOH / CHCl₃ / 55 °C

4.1: NaBH₄ / methanol; CH₂Cl₂ / -78 °C

5.1: TBAF / tetrahydrofuran / 20 °C

6.1: 2,6-lutidine / CH₂Cl₂ / 0.5 h / -78 °C

6.2: CH₂Cl₂

7.1: 89 percent / n-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide / -100 °C

8.1: 74 percent / TsOH / CHCl₃ / 55 °C

9.1: NaBH₄ / methanol; CH₂Cl₂ / -78 °C

10.1: TBAF / tetrahydrofuran / 20 °C

11.1: 2,6-lutidine / CH₂Cl₂ / 0.5 h / -78 °C

11.2: CH₂Cl₂

12.1: 95 percent / n-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide / -100 °C

13.1: 73 percent / TsOH / CHCl₃ / 55 °C

14.1: 2,6-lutidine / CH₂Cl₂ / 0.5 h / -78 °C

14.2: CH₂Cl₂

15.1: 89 percent / n-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide / -100 °C

16.1: 73 percent / TsOH / CHCl₃ / 55 °C

17.1: BF₃*OEt₂ / CH₂Cl₂ / -78 °C

17.2: 56 percent / pyridinium p-toluenesulfonate / methanol / 20 °C

18.1: 80 percent / tetrahydrofuran / 20 °C

19.1: 56 percent / m-CPBA / CH₂Cl₂ / 20 °C

20.1: 92 percent / LiBHEt₃ / tetrahydrofuran / 0 °C

21.1: TBAF / tetrahydrofuran / 20 °C

22.1: 85 percent / 2,6-lutidine / CH₂Cl₂ / 0.5 h / -78 °C

23.1: 85 percent / CH₂Cl₂

24.1: 90 percent / n-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide / -100 °C

25.1: 72 percent / BF₃*OEt₂ / CH₂Cl₂ / 0 °C

With 2,6-dimethylpyridine; sodium tetrahydroborate; n-butyllithium; boron trifluoride diethyl etherate; tetrabutyl ammonium fluoride; lithium triethylborohydride; toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane; chloroform;
DOI:10.1016/S0040-4039(03)00252-1

Reference yield:

: 537036-25-2
(4aS,6R,8aR)-6-(2-benzyloxyethyl)-2,2-di-tert-butyl-6-methyldecahydro-1,3,5-trioxa-2-silanaphthalen-7-one

: 537036-46-7
C₅₇H₇₂O₁₀Si

Guidance literature:: Multi-step reaction with 28 steps

1.1: NaBH₄ / methanol; CH₂Cl₂ / -78 °C

2.1: KH / tetrahydrofuran / 20 °C

3.1: TBAF / tetrahydrofuran / -78 °C

4.1: 2,6-lutidine / CH₂Cl₂ / 0.5 h / -78 °C

4.2: 86 percent / CH₂Cl₂

5.1: 91 percent / n-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide / -100 °C

6.1: 74 percent / TsOH / CHCl₃ / 55 °C

7.1: NaBH₄ / methanol; CH₂Cl₂ / -78 °C

8.1: TBAF / tetrahydrofuran / 20 °C

9.1: 2,6-lutidine / CH₂Cl₂ / 0.5 h / -78 °C

9.2: CH₂Cl₂

10.1: 89 percent / n-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide / -100 °C

11.1: 74 percent / TsOH / CHCl₃ / 55 °C

12.1: NaBH₄ / methanol; CH₂Cl₂ / -78 °C

13.1: TBAF / tetrahydrofuran / 20 °C

14.1: 2,6-lutidine / CH₂Cl₂ / 0.5 h / -78 °C

14.2: CH₂Cl₂

15.1: 95 percent / n-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide / -100 °C

16.1: 73 percent / TsOH / CHCl₃ / 55 °C

17.1: 2,6-lutidine / CH₂Cl₂ / 0.5 h / -78 °C

17.2: CH₂Cl₂

18.1: 89 percent / n-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide / -100 °C

19.1: 73 percent / TsOH / CHCl₃ / 55 °C

20.1: BF₃*OEt₂ / CH₂Cl₂ / -78 °C

20.2: 56 percent / pyridinium p-toluenesulfonate / methanol / 20 °C

21.1: 80 percent / tetrahydrofuran / 20 °C

22.1: 56 percent / m-CPBA / CH₂Cl₂ / 20 °C

23.1: 92 percent / LiBHEt₃ / tetrahydrofuran / 0 °C

24.1: TBAF / tetrahydrofuran / 20 °C

25.1: 85 percent / 2,6-lutidine / CH₂Cl₂ / 0.5 h / -78 °C

26.1: 85 percent / CH₂Cl₂

27.1: 90 percent / n-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide / -100 °C

28.1: 72 percent / BF₃*OEt₂ / CH₂Cl₂ / 0 °C

With 2,6-dimethylpyridine; sodium tetrahydroborate; n-butyllithium; boron trifluoride diethyl etherate; tetrabutyl ammonium fluoride; potassium hydride; lithium triethylborohydride; toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane; chloroform;
DOI:10.1016/S0040-4039(03)00252-1