2-[2-benzoylamino-3-(tert-butyl-diphenyl-silanyloxy)-propionylamino]-3-oxo-propionic acid methyl ester

Base Information

Chemical Name:2-[2-benzoylamino-3-(tert-butyl-diphenyl-silanyloxy)-propionylamino]-3-oxo-propionic acid methyl ester
CAS No.:1354647-34-9
Molecular Formula:C₃₀H₃₄N₂O₆Si
Molecular Weight:546.695
Hs Code.:

Synonyms:2-[2-benzoylamino-3-(tert-butyl-diphenyl-silanyloxy)-propionylamino]-3-oxo-propionic acid methyl ester

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Chemical Property of 2-[2-benzoylamino-3-(tert-butyl-diphenyl-silanyloxy)-propionylamino]-3-oxo-propionic acid methyl ester

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Technology Process of 2-[2-benzoylamino-3-(tert-butyl-diphenyl-silanyloxy)-propionylamino]-3-oxo-propionic acid methyl ester

There total 5 articles about 2-[2-benzoylamino-3-(tert-butyl-diphenyl-silanyloxy)-propionylamino]-3-oxo-propionic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1354647-31-6
2-[2-benzoylamino-3-(tert-butyl-diphenyl-silanyloxy)-propionylamino]-3-hydroxy-propionic acid methyl ester

: 1354647-34-9
2-[2-benzoylamino-3-(tert-butyl-diphenyl-silanyloxy)-propionylamino]-3-oxo-propionic acid methyl ester

Guidance literature:: With 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In ethyl acetate; for 8h; Inert atmosphere; Reflux;
DOI:10.1016/j.tetlet.2011.11.023

Reference yield:

: 1354647-17-8
2-benzoylamino-3-(tert-butyl-diphenyl-silanyloxy)-propionic acid methyl ester

: 1354647-34-9
2-[2-benzoylamino-3-(tert-butyl-diphenyl-silanyloxy)-propionylamino]-3-oxo-propionic acid methyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: lithium hydroxide monohydrate / tetrahydrofuran; water / 1.08 h / 0 - 20 °C / Cooling with ice

1.2: 0 °C / Cooling with ice

2.1: O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate; N-ethyl-N,N-diisopropylamine / N,N-dimethyl-formamide / 18 h / 0 - 20 °C / Inert atmosphere

3.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / ethyl acetate / 8 h / Inert atmosphere; Reflux

With lithium hydroxide monohydrate; O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate; N-ethyl-N,N-diisopropylamine; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; water; ethyl acetate; N,N-dimethyl-formamide;
DOI:10.1016/j.tetlet.2011.11.023

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 1354647-34-9
2-[2-benzoylamino-3-(tert-butyl-diphenyl-silanyloxy)-propionylamino]-3-oxo-propionic acid methyl ester

Guidance literature:: Multi-step reaction with 4 steps

1.1: 1H-imidazole / 15 h / 0 - 20 °C / Inert atmosphere

2.1: lithium hydroxide monohydrate / tetrahydrofuran; water / 1.08 h / 0 - 20 °C / Cooling with ice

2.2: 0 °C / Cooling with ice

3.1: O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate; N-ethyl-N,N-diisopropylamine / N,N-dimethyl-formamide / 18 h / 0 - 20 °C / Inert atmosphere

4.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / ethyl acetate / 8 h / Inert atmosphere; Reflux

With 1H-imidazole; lithium hydroxide monohydrate; O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate; N-ethyl-N,N-diisopropylamine; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; water; ethyl acetate; N,N-dimethyl-formamide;
DOI:10.1016/j.tetlet.2011.11.023