benzylmanganese(II) chloride

Base Information

• Chemical Name: benzylmanganese(II) chloride
• CAS No.: 180069-62-9
• Molecular Formula: C₇H₇ClMn
• Molecular Weight: 181.524
• Mol file: 180069-62-9.mol

Synonyms:benzylmanganese(II) chloride

Chemical Property of benzylmanganese(II) chloride

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of benzylmanganese(II) chloride

There total 2 articles about benzylmanganese(II) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

lithium manganese chloride + benzyl chloride (100-44-7) → benzylmanganese(II) chloride (180069-62-9)

Guidance literature:

With magnesium; In tetrahydrofuran; at 0 ℃; for 1h; Inert atmosphere; Schlenk technique;

DOI:10.1055/s-0036-1589101

Reference yield:

manganese (7439-96-5) + benzyl chloride (100-44-7) → benzylmanganese(II) chloride (180069-62-9)

Guidance literature:

In tetrahydrofuran; (Ar); addn. of C6H5CH2Cl in THF via cannula to stirred at room temp. slurry of highly active Mn in THF; stirring at room temp. for 20 min; monitoring by gas chromy.;

DOI:10.1016/S0022-328X(03)00500-X

Reference yield: 95.0%

1-nitro-2-(4-chlorophenyl)ethylene (101671-01-6,5153-70-8) + benzylmanganese(II) chloride (180069-62-9) → 2-(4-chlorophenyl)-1-nitro-3-phenylpropane

Guidance literature:

In tetrahydrofuran; at -30 ℃;

DOI:10.1016/0022-328X(96)06150-5

upstream raw materials:

manganese

benzyl chloride

Downstream raw materials:

1-nitro-2,3-diphenylpropane

2-nitro-1-benzylcyclohexane

4-benzylbenzonitrile

p-benzylanizole