2-(hydroxyimino)-1-methoxy-4-(3,4-dimethoxyphenyl)bicyclo<2.2.2>oct-5-ene

Base Information

Chemical Name:2-(hydroxyimino)-1-methoxy-4-(3,4-dimethoxyphenyl)bicyclo<2.2.2>oct-5-ene
CAS No.:110417-06-6
Molecular Formula:C₁₇H₂₁NO₄
Molecular Weight:303.358
Hs Code.:

Synonyms:2-(hydroxyimino)-1-methoxy-4-(3,4-dimethoxyphenyl)bicyclo<2.2.2>oct-5-ene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-(hydroxyimino)-1-methoxy-4-(3,4-dimethoxyphenyl)bicyclo<2.2.2>oct-5-ene

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Technology Process of 2-(hydroxyimino)-1-methoxy-4-(3,4-dimethoxyphenyl)bicyclo<2.2.2>oct-5-ene

There total 5 articles about 2-(hydroxyimino)-1-methoxy-4-(3,4-dimethoxyphenyl)bicyclo<2.2.2>oct-5-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 110417-04-4
1-methoxy-4-(3,4-dimethoxyphenyl)-2-oxobicyclo<2.2.2>oct-5-ene

: 110417-06-6
2-(hydroxyimino)-1-methoxy-4-(3,4-dimethoxyphenyl)bicyclo<2.2.2>oct-5-ene

Guidance literature:: With hydroxylamine hydrochloride; sodium acetate; In methanol; water; Heating;
DOI:10.1021/jo00232a032

Reference yield:

: 110417-00-0
1-methoxy-4-(3,4-dimethoxyphenyl)cyclohexa-1,3-diene

: 110417-06-6
2-(hydroxyimino)-1-methoxy-4-(3,4-dimethoxyphenyl)bicyclo<2.2.2>oct-5-ene

Guidance literature:: Multi-step reaction with 3 steps

1: 25.8 percent / phenothiazine / toluene / 5 h / 180 °C

2: 37 percent / Na₂S*9H₂O / ethanol / 42 h / Heating

3: 100 percent / hydroxylamine hydrochloride, sodium acetate / methanol; H₂O / Heating

With sodium sulfide; 10H-phenothiazine; hydroxylamine hydrochloride; sodium acetate; In methanol; ethanol; water; toluene;
DOI:10.1021/jo00232a032

Reference yield:

: 70779-48-5
4-(3,4-Dimethoxy-phenyl)-cyclohex-3-enone

: 110417-06-6
2-(hydroxyimino)-1-methoxy-4-(3,4-dimethoxyphenyl)bicyclo<2.2.2>oct-5-ene

Guidance literature:: Multi-step reaction with 5 steps

1: 70 percent / p-toluenesulfonic acid / methanol / 3 h / Ambient temperature

2: 72 percent / hexamethyldisilazane, iodotrimethylsilane / CH₂Cl₂ / 4 h / -10 - 20 °C

3: 25.8 percent / phenothiazine / toluene / 5 h / 180 °C

4: 37 percent / Na₂S*9H₂O / ethanol / 42 h / Heating

5: 100 percent / hydroxylamine hydrochloride, sodium acetate / methanol; H₂O / Heating

With sodium sulfide; 10H-phenothiazine; trimethylsilyl iodide; hydroxylamine hydrochloride; sodium acetate; toluene-4-sulfonic acid; 1,1,1,3,3,3-hexamethyl-disilazane; In methanol; ethanol; dichloromethane; water; toluene;
DOI:10.1021/jo00232a032