Bis(cycloocta-1,5-diene)rhodium(I) hexafluorophosphate

Base Information

• Chemical Name: Bis(cycloocta-1,5-diene)rhodium(I) hexafluorophosphate
• CAS No.: 62793-31-1
• Molecular Formula: C16H24F18P3Rh
• Molecular Weight: 0
• DSSTox Substance ID: DTXSID70451106
• Mol file: 62793-31-1.mol

Synonyms:62793-31-1;Bis(cycloocta-1,5-diene)rhodium(I) hexafluorophosphate;[rh(cod)2]pf6;(1Z,5Z)-cycloocta-1,5-diene;rhodium;hexafluorophosphate;DTXSID70451106;MolPort-027-836-914;-rhodium(1+) bis((1Z,5Z)-cycloocta-1,5-diene) hexafluoro--phosphanuide

Chemical Property of Bis(cycloocta-1,5-diene)rhodium(I) hexafluorophosphate

Chemical Property:

• PSA: 40.77000
• LogP: 15.49280
• Storage Temp.: Inert atmosphere,Room Temperature
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 0
• Exact Mass: 464.05748
• Heavy Atom Count: 24
• Complexity: 135

Purity/Quality:

97% ^*data from raw suppliers

Bis(cycloocta-1,5-diene)rhodium(I)hexafluorophosphate 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CC=CCCC=C1.C1CC=CCCC=C1.F[P-](F)(F)(F)(F)F.[Rh]
• Isomeric SMILES: C1/C=C\CC/C=C\C1.C1/C=C\CC/C=C\C1.F[P-](F)(F)(F)(F)F.[Rh]

Technology Process of Bis(cycloocta-1,5-diene)rhodium(I) hexafluorophosphate

There total 1 articles about Bis(cycloocta-1,5-diene)rhodium(I) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Rh(1,5-cyclooctadiene)(azulene)](PF6) + cyclo-octa-1,5-diene (5259-72-3,10060-40-9,111-78-4) → [Rh(cyclooctadiene)2](PF6) (62793-31-1)

Guidance literature:

With (C₂H₅)3N; In not given; Rh complex treated with excess of ligand in presence of NEt3 in acetoneor CH2Cl2 at room temp., stirred for 5 min; pptd. by addn. of Et2O;

DOI:10.1016/0022-328X(84)80605-1

Reference yield: 75.0%

[Rh(cyclooctadiene)2](PF6) (62793-31-1) + trans-(1-l-menthyl-2-phenylphosphirane)pentacarbonylmolybdenum → (C8H12)Rh(C2H3P(C10H19)(C6H5))2(1+)*PF6(1-)*CH2Cl2={(C8H12)Rh(C2H3P(C10H19)(C6H5))2}PF6*CH2Cl2

Guidance literature:

With bis(diphenylphosphino)ethane; CH₂Cl₂; In dichloromethane; toluene; pentane; byproducts: (CO)4Mo(bis(diphenylphosphino)ethane), cyclooctadiene; the Mo complex (1.5 mmol) and bis(diphenylphosphino)ethane were heated at 96°C for 15 h in toluene; the formed Mo complex was removed; addn. of CH2Cl2 to the soln.; gradual addn. of the solid Rh complex (0.58 mmol) at room temp.; under Ar;; pptn. by addn. of ether; repeated pptns. from CH2Cl2/ether; elem. anal.;;

DOI:10.1021/om00028a040

Reference yield: 60.0%

[Rh(cyclooctadiene)2](PF6) (62793-31-1) + (C6H5)2PC3H(CH3)4PC6H9(CH3)CH(CH3)2 → Rh(C8H12)((C6H5)2PC3H(CH3)4PC6H9(CH3)CH(CH3)2)(1+)*PF6(1-)=[Rh(C8H12)((C6H5)2PC3H(CH3)4PC6H9(CH3)CH(CH3)2)]PF6 (172266-27-2)

Guidance literature:

In dichloromethane; room temp.; crystn. on concg. and ether addn. (-20°C, overnight); elem. anal.;

DOI:10.1021/om00011a006

upstream raw materials:

cyclo-octa-1,5-diene

Downstream raw materials:

Rh(C₈H₁₂)C₄H₆{CH₂P(C₆H₄SO₃)2}2^(3-)*4Na⁽¹⁺⁾=Na₄Rh(C₈H₁₂)C₄H₆{CH₂P(C₆H₄SO₃)2}2⁽¹⁺⁾

{Rh(PCy₃)2(MeCN)2H₂}PF₆

(C₈H₁₂)Rh(C₂H₃P(C(CH₃)3)(C₆H₅))2⁽¹⁺⁾*PF₆^(1-)={(C₈H₁₂)Rh(C₂H₃P(C₄H₉)(C₆H₅))2}PF₆

Rh(C₈H₁₂)((C₆H₅)2PC₃H(CH₃)4PC₆H₉(CH₃)CH(CH₃)2)⁽¹⁺⁾*PF₆^(1-)=[Rh(C₈H₁₂)((C₆H₅)2PC₃H(CH₃)4PC₆H₉(CH₃)CH(CH₃)2)]PF₆

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