1,6-anhydro-3-C-{2,6-anhydro-1-deoxy-3,4,5,7-tetra-O-[(tert-butyl)dimethylsilyl]-D-glycero-L-mannoheptitol-1-C-yl}-2-[(benzyl)(methoxy)amino]-2,3-dideoxy-β-D-galactohexopyranose

Base Information

Chemical Name:1,6-anhydro-3-C-{2,6-anhydro-1-deoxy-3,4,5,7-tetra-O-[(tert-butyl)dimethylsilyl]-D-glycero-L-mannoheptitol-1-C-yl}-2-[(benzyl)(methoxy)amino]-2,3-dideoxy-β-D-galactohexopyranose
CAS No.:1403496-92-3
Molecular Formula:C₄₅H₈₇NO₉Si₄
Molecular Weight:898.529
Hs Code.:

1,6-anhydro-3-C-{2,6-anhydro-1-deoxy-3,4,5,7-tetra-O-[(tert-butyl)dimethylsilyl]-D-glycero-L-mannoheptitol-1-C-yl}-2-[(benzyl)(methoxy)amino]-2,3-dideoxy-β-D-galactohexopyranose

Synonyms:1,6-anhydro-3-C-{2,6-anhydro-1-deoxy-3,4,5,7-tetra-O-[(tert-butyl)dimethylsilyl]-D-glycero-L-mannoheptitol-1-C-yl}-2-[(benzyl)(methoxy)amino]-2,3-dideoxy-β-D-galactohexopyranose

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Chemical Property of 1,6-anhydro-3-C-{2,6-anhydro-1-deoxy-3,4,5,7-tetra-O-[(tert-butyl)dimethylsilyl]-D-glycero-L-mannoheptitol-1-C-yl}-2-[(benzyl)(methoxy)amino]-2,3-dideoxy-β-D-galactohexopyranose

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Technology Process of 1,6-anhydro-3-C-{2,6-anhydro-1-deoxy-3,4,5,7-tetra-O-[(tert-butyl)dimethylsilyl]-D-glycero-L-mannoheptitol-1-C-yl}-2-[(benzyl)(methoxy)amino]-2,3-dideoxy-β-D-galactohexopyranose

There total 11 articles about 1,6-anhydro-3-C-{2,6-anhydro-1-deoxy-3,4,5,7-tetra-O-[(tert-butyl)dimethylsilyl]-D-glycero-L-mannoheptitol-1-C-yl}-2-[(benzyl)(methoxy)amino]-2,3-dideoxy-β-D-galactohexopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 1,6-anhydro-3-{2,6-anhydro-1-deoxy-3,4,5,7-tetra-O-[(tert-butyl)dimethylsilyl]-D-glycero-L-mannoheptitol-1-C-yl}-2-[(N-benzyl-N-methoxy)amino]-2,3-dideoxy-β-D-xylohexopyran-4-ulose

: 1403496-92-3
1,6-anhydro-3-C-{2,6-anhydro-1-deoxy-3,4,5,7-tetra-O-[(tert-butyl)dimethylsilyl]-D-glycero-L-mannoheptitol-1-C-yl}-2-[(benzyl)(methoxy)amino]-2,3-dideoxy-β-D-galactohexopyranose

Guidance literature:: With lithium borohydride; In tetrahydrofuran; at -78 - -40 ℃;
DOI:10.1002/chem.201200364

Reference yield:

: C₈H₁₄O₇

: 1403496-92-3
1,6-anhydro-3-C-{2,6-anhydro-1-deoxy-3,4,5,7-tetra-O-[(tert-butyl)dimethylsilyl]-D-glycero-L-mannoheptitol-1-C-yl}-2-[(benzyl)(methoxy)amino]-2,3-dideoxy-β-D-galactohexopyranose

Guidance literature:: Multi-step reaction with 7 steps

1.1: pyridine; dmap / 24 h / 20 °C

2.1: diisobutylaluminium hydride / hexane; toluene / 0.5 h / 0 °C

3.1: diethylaluminum iodide / dichloromethane; toluene / -90 - -76 °C

4.1: 12 h / 20 °C

5.1: pyridine; trifluoroacetic anhydride / dichloromethane / 1 h / 0 °C

5.2: 0.33 h / 0 °C

6.1: hydrogen / ethanol / 70 °C / 38002.6 Torr

7.1: lithium borohydride / tetrahydrofuran / -78 - -40 °C

With pyridine; dmap; lithium borohydride; hydrogen; diethylaluminum iodide; diisobutylaluminium hydride; trifluoroacetic anhydride; In tetrahydrofuran; ethanol; hexane; dichloromethane; toluene; 3.1: Itoh-Nozaki condensation;
DOI:10.1002/chem.201200364

Reference yield:

: C₃₂H₇₀O₇Si₄

: 1403496-92-3
1,6-anhydro-3-C-{2,6-anhydro-1-deoxy-3,4,5,7-tetra-O-[(tert-butyl)dimethylsilyl]-D-glycero-L-mannoheptitol-1-C-yl}-2-[(benzyl)(methoxy)amino]-2,3-dideoxy-β-D-galactohexopyranose

Guidance literature:: Multi-step reaction with 6 steps

1.1: diisobutylaluminium hydride / hexane; toluene / 0.5 h / 0 °C

2.1: diethylaluminum iodide / dichloromethane; toluene / -90 - -76 °C

3.1: 12 h / 20 °C

4.1: pyridine; trifluoroacetic anhydride / dichloromethane / 1 h / 0 °C

4.2: 0.33 h / 0 °C

5.1: hydrogen / ethanol / 70 °C / 38002.6 Torr

6.1: lithium borohydride / tetrahydrofuran / -78 - -40 °C

With pyridine; lithium borohydride; hydrogen; diethylaluminum iodide; diisobutylaluminium hydride; trifluoroacetic anhydride; In tetrahydrofuran; ethanol; hexane; dichloromethane; toluene; 2.1: Itoh-Nozaki condensation;
DOI:10.1002/chem.201200364