methyl 6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-2,3,4-tri-O-benzoyl-α-D-glucopyranoside

Base Information

• Chemical Name: methyl 6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-2,3,4-tri-O-benzoyl-α-D-glucopyranoside
• CAS No.: 125135-28-6
• Molecular Formula: C₆₂H₅₂O₁₈
• Molecular Weight: 1085.08
• Mol file: 125135-28-6.mol

Synonyms:methyl 6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-2,3,4-tri-O-benzoyl-α-D-glucopyranoside

Chemical Property of methyl 6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-2,3,4-tri-O-benzoyl-α-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-2,3,4-tri-O-benzoyl-α-D-glucopyranoside

There total 50 articles about methyl 6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-2,3,4-tri-O-benzoyl-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

methyl 2,3,4-tri-O-benzoylglucopyranoside (34234-44-1) + ortho-(para-methoxyphenylethynyl)phenyl 2,3,4,6-tetra-O-benzoyl-β-D-glucopyranoside → methyl 6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-2,3,4-tri-O-benzoyl-α-D-glucopyranoside (125135-28-6)

Guidance literature:

methyl 2,3,4-tri-O-benzoylglucopyranoside; ortho-(para-methoxyphenylethynyl)phenyl 2,3,4,6-tetra-O-benzoyl-β-D-glucopyranoside; In dichloromethane; at 20 ℃; for 0.5h; Molecular sieve;

With N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -35 ℃; for 3.5h; Reagent/catalyst; Molecular sieve;

DOI:10.1021/jacs.7b07020

Reference yield: 99.0%

methyl 2,3,4-tri-O-benzoylglucopyranoside (34234-44-1) + 2,3,4,6-tetra-O-benzoyl-α-D-glucopyranosyl p-trifluoromethylbenzylthio-p-trifluoromethylphenyl formimidate (428816-48-2) → methyl 6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-2,3,4-tri-O-benzoyl-α-D-glucopyranoside (125135-28-6) + (4-trifluoromethyl-phenyl)-thiocarbamic acid S-(4-trifluoromethyl-benzyl) ester

Guidance literature:

With hydrogen tetrakis(pentafluorophenyl)borate; MS 5 Angstroem; In dichloromethane; at 0 ℃; for 1h;

DOI:10.1246/cl.2002.392

Reference yield: 98.0%

methyl 2,3,4-tri-O-benzoylglucopyranoside (34234-44-1) + ethyl 2,3,4,6-tetra-O-benzoyl-1-thio-β-D-galactopyranoside (105376-04-3,113214-71-4,138661-53-7) → methyl (2,3,4,6-tetra-O-benzoyl-β-D-galactopyranosyl)-(1->6)-2,3,4-tri-O-benzoyl-α-D-glucopyranoside (91318-11-5,106863-70-1,107911-43-3,125135-28-6,138752-83-7,143292-66-4,149818-84-8,131723-39-2)

Guidance literature:

With N-iodo-succinimide; 5A molecular sieve; trifluorormethanesulfonic acid; In diethyl ether; 1,2-dichloro-ethane; at 0 ℃; for 0.00833333h;

DOI:10.1016/S0040-4039(00)88799-7

upstream raw materials:

methyl 2,3,4-tri-O-benzoylglucopyranoside

ethyl 2,3,4,6-tetra-O-benzoyl-1-thio-β-D-galactopyranoside

C₃₈H₃₉N₂O₁₁P

tetrabenzoylglucopyranosyl diphenyl phosphate

Downstream raw materials:

methyl 6-O-(2,3,4,6-tetra-O-benzoyl-α-D-glucopyranosyl)-2,3,4-tri-O-benzoyl-α-D-glucopyranoside