tert-Butyl-[(1S,3S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-methyl-4-(2-methyl-[1,3]dithian-2-yl)-butoxy]-diphenyl-silane

Base Information

Chemical Name:tert-Butyl-[(1S,3S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-methyl-4-(2-methyl-[1,3]dithian-2-yl)-butoxy]-diphenyl-silane
CAS No.:218439-42-0
Molecular Formula:C₃₁H₄₆O₃S₂Si
Molecular Weight:558.922
Hs Code.:

Synonyms:tert-Butyl-[(1S,3S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-methyl-4-(2-methyl-[1,3]dithian-2-yl)-butoxy]-diphenyl-silane

Suppliers and Price of tert-Butyl-[(1S,3S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-methyl-4-(2-methyl-[1,3]dithian-2-yl)-butoxy]-diphenyl-silane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of tert-Butyl-[(1S,3S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-methyl-4-(2-methyl-[1,3]dithian-2-yl)-butoxy]-diphenyl-silane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of tert-Butyl-[(1S,3S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-methyl-4-(2-methyl-[1,3]dithian-2-yl)-butoxy]-diphenyl-silane

There total 11 articles about tert-Butyl-[(1S,3S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-methyl-4-(2-methyl-[1,3]dithian-2-yl)-butoxy]-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 58479-61-1
tert-butylchlorodiphenylsilane

: 218439-41-9
(1S,3S)-1-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-3-methyl-4-(2-methyl-[1,3]dithian-2-yl)-butan-1-ol

: 218439-42-0
tert-Butyl-[(1S,3S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-methyl-4-(2-methyl-[1,3]dithian-2-yl)-butoxy]-diphenyl-silane

Guidance literature:: With 1H-imidazole; dmap; In N,N-dimethyl-formamide; at 50 ℃;
DOI:10.1246/bcsj.71.2433

Reference yield:

: 108275-53-2
(2R,3R)-3,4-O-isopropylidene-2-[(tert-butyldimethylsilyl)oxy]-3,4-dihydroxybutanal

: 218439-42-0
tert-Butyl-[(1S,3S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-methyl-4-(2-methyl-[1,3]dithian-2-yl)-butoxy]-diphenyl-silane

Guidance literature:: Multi-step reaction with 9 steps

1: 7.72 g / benzene / 50 °C

2: 99 percent / H₂ / Pd/C / ethanol / 5 h / Ambient temperature

3: 83 percent / LDA / tetrahydrofuran / 1 h / -30 °C

4: 88 percent / LiAlH₄ / tetrahydrofuran / 1 h / 0 °C

5: 100 percent / pyridine / Ambient temperature

6: 89 percent / NaI / acetone / Heating

7: 100 percent / t-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide; pentane / 1 h / -78 °C

8: 88 percent / n-Bu₄NF / tetrahydrofuran / Ambient temperature

9: 100 percent / imidazole, 4-dimethylaminopyridine / dimethylformamide / 50 °C

With 1H-imidazole; dmap; lithium aluminium tetrahydride; tetrabutyl ammonium fluoride; hydrogen; tert.-butyl lithium; sodium iodide; lithium diisopropyl amide; palladium on activated charcoal; In tetrahydrofuran; pyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; ethanol; N,N-dimethyl-formamide; acetone; pentane; benzene;
DOI:10.1246/bcsj.71.2433

Reference yield:

: 76706-83-7
3,4-O-Isopropyliden-D-erythrose-trimethylendithioacetal

: 218439-42-0
tert-Butyl-[(1S,3S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-methyl-4-(2-methyl-[1,3]dithian-2-yl)-butoxy]-diphenyl-silane

Guidance literature:: Multi-step reaction with 11 steps

1: 93 percent / 2,6-lutidine / CH₂Cl₂ / Ambient temperature

2: 6.05 g / Hg(ClO₄)2, CaCO₃ / tetrahydrofuran; H₂O / 0.75 h / Ambient temperature

3: 7.72 g / benzene / 50 °C

4: 99 percent / H₂ / Pd/C / ethanol / 5 h / Ambient temperature

5: 83 percent / LDA / tetrahydrofuran / 1 h / -30 °C

6: 88 percent / LiAlH₄ / tetrahydrofuran / 1 h / 0 °C

7: 100 percent / pyridine / Ambient temperature

8: 89 percent / NaI / acetone / Heating

9: 100 percent / t-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide; pentane / 1 h / -78 °C

10: 88 percent / n-Bu₄NF / tetrahydrofuran / Ambient temperature

11: 100 percent / imidazole, 4-dimethylaminopyridine / dimethylformamide / 50 °C

With 1H-imidazole; 2,6-dimethylpyridine; dmap; lithium aluminium tetrahydride; mercury(II) perchlorate; tetrabutyl ammonium fluoride; hydrogen; tert.-butyl lithium; calcium carbonate; sodium iodide; lithium diisopropyl amide; palladium on activated charcoal; In tetrahydrofuran; pyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; ethanol; dichloromethane; water; N,N-dimethyl-formamide; acetone; pentane; benzene;
DOI:10.1246/bcsj.71.2433