tricarbonyl(benzyidenemethyl butyl ketone)iron⁽⁰⁾

Base Information

Chemical Name:tricarbonyl(benzyidenemethyl butyl ketone)iron⁽⁰⁾
CAS No.:112515-13-6
Molecular Formula:C₁₆H₁₆FeO₄
Molecular Weight:328.148
Hs Code.:

tricarbonyl(benzyidenemethyl butyl ketone)iron<sup>(0)</sup>

Synonyms:tricarbonyl(benzyidenemethyl butyl ketone)iron⁽⁰⁾

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Chemical Property of tricarbonyl(benzyidenemethyl butyl ketone)iron⁽⁰⁾

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Technology Process of tricarbonyl(benzyidenemethyl butyl ketone)iron⁽⁰⁾

There total 1 articles about tricarbonyl(benzyidenemethyl butyl ketone)iron⁽⁰⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 15321-51-4
diiron nonacarbonyl

: 4071-84-5
1-phenyl-hept-1-en-3-one

: 112515-13-6
tricarbonyl(benzyidenemethyl butyl ketone)iron⁽⁰⁾

Guidance literature:: In diethyl ether; 2 equivalents of Fe compd. and carbonyl compd. were heated in Et2O for 15-18 h;
DOI:10.1039/c39890000021

Reference yield: 73.0%

: 112515-13-6
tricarbonyl(benzyidenemethyl butyl ketone)iron⁽⁰⁾

: 917-54-4
methyllithium

: 112481-14-8
3-phenylnonane-2,5-dione

Guidance literature:: With (CH₃)3CBr; In diethyl ether; addn. of MeLi to Fe-complex in diethyl ether at -78°C (under N2), stirring at -78°C for 7 h, treatment with (CH3)3CBr at -78°C, allowing to warm to room temp.; filtration through alumina, column chromy. (SiO2, light petroleum-diethyl ether, 9:1);

Reference yield: 48.0%

: 112515-13-6
tricarbonyl(benzyidenemethyl butyl ketone)iron⁽⁰⁾

: 917-54-4
methyllithium

: 123543-13-5
tricarbonyl(3-butyl-5-phenyl-1-oxapenta-1,2,4-triene)iron⁽⁰⁾

Guidance literature:: With C(CH₃)3Br; In tetrahydrofuran; carbonyl compd. and MeLi was stirred at -78°C in THF for 2 h under CO atmosphere (1,1 atm.), then tBuBr was added and stirred for further 0,5 h at the same temp., mixt. was then allowed to warm up to room temp. over 1 h under CO; soln. filtered through alumina and chromd.;
DOI:10.1039/c39890000021