η₄-{1,3-diphenyl-4,5,6,7-tetrahydro-2H-inden-2-one}iron⁰ tricarbonyl

Base Information

• Chemical Name: η₄-{1,3-diphenyl-4,5,6,7-tetrahydro-2H-inden-2-one}iron⁰ tricarbonyl
• CAS No.: 144269-95-4
• Molecular Formula: C₂₄H₁₈FeO₄
• Molecular Weight: 426.252
• Mol file: 144269-95-4.mol

Synonyms:η₄-{1,3-diphenyl-4,5,6,7-tetrahydro-2H-inden-2-one}iron⁰ tricarbonyl

Chemical Property of η₄-{1,3-diphenyl-4,5,6,7-tetrahydro-2H-inden-2-one}iron⁰ tricarbonyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of η₄-{1,3-diphenyl-4,5,6,7-tetrahydro-2H-inden-2-one}iron⁰ tricarbonyl

There total 2 articles about η₄-{1,3-diphenyl-4,5,6,7-tetrahydro-2H-inden-2-one}iron⁰ tricarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

iron pentacarbonyl (13463-40-6,37220-42-1) + 1,8-diphenyl-1,7-octadiyne (13225-62-2) → η4-{1,3-diphenyl-4,5,6,7-tetrahydro-2H-inden-2-one}iron0 tricarbonyl (144269-95-4)

Guidance literature:

In toluene; at 140 ℃; for 24h; under 5250.53 - 7500.75 Torr; Microwave irradiation; Sealed tube; Schlenk technique; Inert atmosphere;

DOI:10.1039/d1dt01252e

Reference yield:

C24H19FeO4(1+)*BF4(1-) → η4-{1,3-diphenyl-4,5,6,7-tetrahydro-2H-inden-2-one}iron0 tricarbonyl (144269-95-4)

Guidance literature:

With triethylamine; Inert atmosphere;

DOI:10.1007/s11243-018-0229-1

Reference yield: 28.0%

η4-{1,3-diphenyl-4,5,6,7-tetrahydro-2H-inden-2-one}iron0 tricarbonyl (144269-95-4) + acetonitrile (75-05-8,26809-02-9) → η4-{1,3-diphenyl-4,5,6,7-tetrahydro-2H-inden-2-one}iron0 dicarbonyl mono-acetonitrile

Guidance literature:

With trimethylamine-N-oxide; at 25 ℃; for 3h; Inert atmosphere; Schlenk technique; Darkness;

DOI:10.1039/d1dt01252e

upstream raw materials:

iron pentacarbonyl

1,8-diphenyl-1,7-octadiyne