Cyclohexaneethanol, 2-methylene-, 1-(4-methylbenzenesulfonate)

Base Information

Chemical Name:Cyclohexaneethanol, 2-methylene-, 1-(4-methylbenzenesulfonate)
CAS No.:41825-83-6
Molecular Formula:C₁₆H₂₂O₃S
Molecular Weight:294.415
Hs Code.:
DSSTox Substance ID:DTXSID501176487

Synonyms:DTXSID501176487;Cyclohexaneethanol, 2-methylene-, 1-(4-methylbenzenesulfonate);41825-83-6

Suppliers and Price of Cyclohexaneethanol, 2-methylene-, 1-(4-methylbenzenesulfonate)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Cyclohexaneethanol, 2-methylene-, 1-(4-methylbenzenesulfonate)

Chemical Property:

XLogP3:4.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:5
Exact Mass:294.12896573
Heavy Atom Count:20
Complexity:414

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=CC=C(C=C1)S(=O)(=O)OCCC2CCCCC2=C

Technology Process of Cyclohexaneethanol, 2-methylene-, 1-(4-methylbenzenesulfonate)

There total 5 articles about Cyclohexaneethanol, 2-methylene-, 1-(4-methylbenzenesulfonate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 53544-46-0
2-(1-methylenecyclohex-2-yl)ethan-1-ol

: 104-15-4
toluene-4-sulfonic acid

: 41825-83-6
2-<2-(β-toluenesulfonyloxy)ethyl>-1-methylenecyclohexane

Guidance literature:: With 1,4-diaza-bicyclo[2.2.2]octane; In dichloromethane; at 0 - 20 ℃; for 2.08333h;
DOI:10.1039/c4ob01266f

Reference yield: 70.0%

: 53544-46-0
2-(1-methylenecyclohex-2-yl)ethan-1-ol

: 98-59-9
p-toluenesulfonyl chloride

: 41825-83-6
2-<2-(β-toluenesulfonyloxy)ethyl>-1-methylenecyclohexane

Guidance literature:: With pyridine; In benzene; 1.) 5 deg C, 15 h, 2.) 20 deg C, 3 d;
DOI:10.1021/jo00344a016

Reference yield:

: 4845-04-9
1-cyclohexene-1-methanol

: 41825-83-6
2-<2-(β-toluenesulfonyloxy)ethyl>-1-methylenecyclohexane

Guidance literature:: Multi-step reaction with 3 steps

1: 77 percent / propionic acid / 18 h / 138 °C

2: 77 percent / LiAlH₄ / diethyl ether / 3 h / Heating

3: 70 percent / pyridine / benzene / 1.) 5 deg C, 15 h, 2.) 20 deg C, 3 d

With pyridine; lithium aluminium tetrahydride; propionic acid; In diethyl ether; benzene;
DOI:10.1021/jo00344a016