C₁₁H₁₅BrMgSi

Base Information

• Chemical Name: C₁₁H₁₅BrMgSi
• CAS No.: 78133-20-7
• Molecular Formula: C₁₁H₁₅BrMgSi
• Molecular Weight: 279.535
• Mol file: 78133-20-7.mol

Synonyms:C₁₁H₁₅BrMgSi

Chemical Property of C₁₁H₁₅BrMgSi

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of C₁₁H₁₅BrMgSi

There total 3 articles about C₁₁H₁₅BrMgSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

isobutylmagnesium bromide (926-62-5) + 1-Phenyl-2-(trimethylsilyl)acetylene (2170-06-1) → C11H15BrMgSi (78133-20-7)

Guidance literature:

With bis(cyclopentadienyl)titanium dichloride; In diethyl ether; at 25 ℃; for 6h;

DOI:10.1002/ejoc.200501002

Reference yield:

1-Phenyl-2-(trimethylsilyl)acetylene (2170-06-1) → C11H15BrMgSi (78133-20-7)

Guidance literature:

With bis(cyclopentadienyl)titanium dichloride; isobutylmagnesium bromide; In diethyl ether; at 0 - 25 ℃; for 6h; Inert atmosphere;

DOI:10.1021/jacs.1c01194

Reference yield:

1-Phenyl-2-(trimethylsilyl)acetylene (2170-06-1) → C11H15BrMgSi (78133-20-7) + C11H15BrMgSi (78133-21-8,120093-96-1)

Guidance literature:

With bis(cyclopentadienyl)titanium dichloride; isobutylmagnesium bromide; In diethyl ether; for 6h; Title compound not separated from byproducts; Ambient temperature;

DOI:10.1016/0040-4039(81)80047-0

upstream raw materials:

1-Phenyl-2-(trimethylsilyl)acetylene

isobutylmagnesium bromide

Downstream raw materials:

(E)-1,1-dimethyl-2-phenyl-3-trimethylsilyl-2-propen-1-ol