Technology Process of Tl[nido-7-[1'-(closo-1',2'-C2B10H11)]-7,8-C2B9H11]*1.25(benzene)
There total 1 articles about Tl[nido-7-[1'-(closo-1',2'-C2B10H11)]-7,8-C2B9H11]*1.25(benzene) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
potassium hydroxide; benzene;
In
ethanol; water;
under N2 or Ar, to soln. of KOH in ethanol added bis(carborane), stirred and heated to reflux for 1.5 h, cooled to room temp., rotary evapd., dissolved in water, TlOAc added; ppt. collected by filtration, dried in vac., recrystd. from glacial acetic acid/benzene, washed with benzene, dried in vac.; elem. anal.;
DOI:10.1021/ja00322a039
- Guidance literature:
-
In
benzene;
under N2 or Ar, reagents and benzene stirred at room temp. for 3 h; filtered through Celite, concd. in vac., layered with ethanol, crystalsisolated by filtration, washed with ethanol, dried in vac.; elem. anal.;
DOI:10.1021/ja00322a039
