S-tert-Butyl (2R,3S)-2-(benzyloxy)-3-<<<(S)-1-phenylethyl>amino>carboxy>-6-methyl-4-heptynethioate

Base Information

Chemical Name:S-tert-Butyl (2R,3S)-2-(benzyloxy)-3-<<<(S)-1-phenylethyl>amino>carboxy>-6-methyl-4-heptynethioate
CAS No.:171755-82-1
Molecular Formula:C₂₈H₃₅NO₄S
Molecular Weight:481.656
Hs Code.:

Synonyms:S-tert-Butyl (2R,3S)-2-(benzyloxy)-3-<<<(S)-1-phenylethyl>amino>carboxy>-6-methyl-4-heptynethioate

Suppliers and Price of S-tert-Butyl (2R,3S)-2-(benzyloxy)-3-<<<(S)-1-phenylethyl>amino>carboxy>-6-methyl-4-heptynethioate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of S-tert-Butyl (2R,3S)-2-(benzyloxy)-3-<<<(S)-1-phenylethyl>amino>carboxy>-6-methyl-4-heptynethioate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of S-tert-Butyl (2R,3S)-2-(benzyloxy)-3-<<<(S)-1-phenylethyl>amino>carboxy>-6-methyl-4-heptynethioate

There total 4 articles about S-tert-Butyl (2R,3S)-2-(benzyloxy)-3-<<<(S)-1-phenylethyl>amino>carboxy>-6-methyl-4-heptynethioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 133756-18-0
S-tert-butyl 2-(benzyloxy)ethanethioate

: 171755-82-1
S-tert-Butyl (2R,3S)-2-(benzyloxy)-3-<<<(S)-1-phenylethyl>amino>carboxy>-6-methyl-4-heptynethioate

Guidance literature:: DOI:10.1021/jo00123a030

Reference yield:

: 14649-03-7
(S)-phenylethyl isocyanate

: S-tert-Butyl (2R*,3S*)-2-(benzyloxy)-3-hydroxy-6-methyl-4-heptynethioate

: 171755-81-0
S-tert-Butyl (2S,3R)-2-(benzyloxy)-3-<<<(S)-1-phenylethyl>amino>carboxy>-6-methyl-4-heptynethioate

: 171755-82-1
S-tert-Butyl (2R,3S)-2-(benzyloxy)-3-<<<(S)-1-phenylethyl>amino>carboxy>-6-methyl-4-heptynethioate

Guidance literature:: With 2-(N,N-dimethylamino)ethanol; dicobalt octacarbonyl; ammonium cerium(IV) nitrate; Multistep reaction; 1.) benzene, reflux, 2.) Et₂O; column chromatography, 3.) MeOH, 0 deg C;
DOI:10.1016/0040-4039(94)85036-4

Reference yield:

: 119775-54-1
4-methylpent-2-ynal

: 171755-82-1
S-tert-Butyl (2R,3S)-2-(benzyloxy)-3-<<<(S)-1-phenylethyl>amino>carboxy>-6-methyl-4-heptynethioate

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) Co₂(CO)8, 2.) BF₃*OEt₂, 3.) CAN / 2.) CH₂Cl₂, -78 deg C, 3.) MeOH, 0 deg C

2: 1.) N,N-dimethylethanolamine, 2.) Co₂(CO)8, 3.) CAN / 1.) benzene, reflux, 2.) Et₂O; column chromatography, 3.) MeOH, 0 deg C

With 2-(N,N-dimethylamino)ethanol; dicobalt octacarbonyl; ammonium cerium(IV) nitrate; boron trifluoride diethyl etherate;
DOI:10.1016/0040-4039(94)85036-4