5,15-di-(3-(2-methoxymalonyloxyethoxy)phenyl)-10,20-diphenyl-copper(II)porphyrin

Base Information

• Chemical Name: 5,15-di-(3-(2-methoxymalonyloxyethoxy)phenyl)-10,20-diphenyl-copper(II)porphyrin
• CAS No.: 1173197-93-7
• Molecular Formula: C₅₆H₄₄CuN₄O₁₀
• Molecular Weight: 996.532
• Mol file: 1173197-93-7.mol

Synonyms:5,15-di-(3-(2-methoxymalonyloxyethoxy)phenyl)-10,20-diphenyl-copper(II)porphyrin

Chemical Property of 5,15-di-(3-(2-methoxymalonyloxyethoxy)phenyl)-10,20-diphenyl-copper(II)porphyrin

Chemical Property:

Purity/Quality:

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Technology Process of 5,15-di-(3-(2-methoxymalonyloxyethoxy)phenyl)-10,20-diphenyl-copper(II)porphyrin

There total 2 articles about 5,15-di-(3-(2-methoxymalonyloxyethoxy)phenyl)-10,20-diphenyl-copper(II)porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

5,15-di-(3-(2-methoxymalonyloxyethoxy)phenyl)-10,20-diphenylporphyrin → 5,15-di-(3-(2-methoxymalonyloxyethoxy)phenyl)-10,20-diphenyl-copper(II)porphyrin (1173197-93-7)

Guidance literature:

With copper diacetate; In methanol; dichloromethane; at 20 ℃; for 2h;

DOI:10.1021/ja9029686

Reference yield: 78.0%

copper(II) acetate dihydrate + (CH3CO2CH2CO2C2H4OC6H4)2(C6H5)2C20H8N4H2 → 5,15-di-(3-(2-methoxymalonyloxyethoxy)phenyl)-10,20-diphenyl-copper(II)porphyrin (1173197-93-7)

Guidance literature:

In methanol; dichloromethane; CH3COH, CH2Cl2, room temp.; column chromy. on silica;

DOI:10.1021/ja9029686

Reference yield: 46.0%

5,15-di-(3-(2-methoxymalonyloxyethoxy)phenyl)-10,20-diphenyl-copper(II)porphyrin (1173197-93-7) + fullerene-C60 (99685-96-8,161105-99-3,161106-00-9,111138-12-6,133318-63-5,134053-11-5,134931-35-4,134931-36-5,139703-76-7,145633-27-8,175414-73-0,175414-74-1,175414-75-2,175519-12-7,175519-13-8,175519-14-9,175519-15-0,136376-46-0,144906-37-6,144906-38-7,151767-00-9,152882-97-8,152882-98-9,152882-99-0,153062-34-1,154171-74-1,154171-75-2,154333-99-0,154334-00-6,154397-63-4,154460-59-0,199456-56-9,108739-25-9,120329-57-9,120329-58-0) → C116H40CuN4O10

Guidance literature:

With iodine; 1,8-diazabicyclo[5.4.0]undec-7-ene; In toluene; at 20 ℃;

DOI:10.1021/ja9029686