tert-butyl 2-phenyl-2,3,4,7,8,9-hexahydro-1H-1,2-diazonine-1-carboxylate

Base Information

Chemical Name:tert-butyl 2-phenyl-2,3,4,7,8,9-hexahydro-1H-1,2-diazonine-1-carboxylate
CAS No.:1355612-36-0
Molecular Formula:C₁₈H₂₆N₂O₂
Molecular Weight:302.417
Hs Code.:

Synonyms:tert-butyl 2-phenyl-2,3,4,7,8,9-hexahydro-1H-1,2-diazonine-1-carboxylate

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Chemical Property of tert-butyl 2-phenyl-2,3,4,7,8,9-hexahydro-1H-1,2-diazonine-1-carboxylate

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Technology Process of tert-butyl 2-phenyl-2,3,4,7,8,9-hexahydro-1H-1,2-diazonine-1-carboxylate

There total 3 articles about tert-butyl 2-phenyl-2,3,4,7,8,9-hexahydro-1H-1,2-diazonine-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

: 1355612-25-7
tert-butyl 2-(but-3-enyl)-1-(pent-4-enyl)-2-phenylhydrazinecarboxylate

: 1355612-36-0
tert-butyl 2-phenyl-2,3,4,7,8,9-hexahydro-1H-1,2-diazonine-1-carboxylate

Guidance literature:: With Grubbs catalyst first generation; In dichloromethane; at 20 ℃; for 24h; Inert atmosphere;
DOI:10.1016/j.tet.2011.11.091

Reference yield:

: 42116-43-8
tert-butyl 2-phenylhydrazine-1-carboxylate

: 1355612-36-0
tert-butyl 2-phenyl-2,3,4,7,8,9-hexahydro-1H-1,2-diazonine-1-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 0.25 h / -78 - -40 °C / Inert atmosphere

1.2: 1 h / Inert atmosphere

2.1: potassium carbonate; sodium hydroxide / toluene / 20 °C

3.1: Grubbs catalyst first generation / dichloromethane / 24 h / 20 °C / Inert atmosphere

With Grubbs catalyst first generation; n-butyllithium; potassium carbonate; sodium hydroxide; In tetrahydrofuran; hexane; dichloromethane; toluene;
DOI:10.1016/j.tet.2011.11.091

Reference yield:

: 1355612-19-9
tert-butyl 2-(but-3-enyl)-2-phenylhydrazinecarboxylate

: 1355612-36-0
tert-butyl 2-phenyl-2,3,4,7,8,9-hexahydro-1H-1,2-diazonine-1-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: potassium carbonate; sodium hydroxide / toluene / 20 °C

2: Grubbs catalyst first generation / dichloromethane / 24 h / 20 °C / Inert atmosphere

With Grubbs catalyst first generation; potassium carbonate; sodium hydroxide; In dichloromethane; toluene;
DOI:10.1016/j.tet.2011.11.091