tert-butyl-{2-[3-(4-methoxy-benzyloxymethyl)-oxiran-2-yl]-allyloxy}-dimethylsilane

Base Information

Chemical Name:tert-butyl-{2-[3-(4-methoxy-benzyloxymethyl)-oxiran-2-yl]-allyloxy}-dimethylsilane
CAS No.:288097-98-3
Molecular Formula:C₂₀H₃₂O₄Si
Molecular Weight:364.557
Hs Code.:

Synonyms:tert-butyl-{2-[3-(4-methoxy-benzyloxymethyl)-oxiran-2-yl]-allyloxy}-dimethylsilane

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Chemical Property of tert-butyl-{2-[3-(4-methoxy-benzyloxymethyl)-oxiran-2-yl]-allyloxy}-dimethylsilane

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Technology Process of tert-butyl-{2-[3-(4-methoxy-benzyloxymethyl)-oxiran-2-yl]-allyloxy}-dimethylsilane

There total 1 articles about tert-butyl-{2-[3-(4-methoxy-benzyloxymethyl)-oxiran-2-yl]-allyloxy}-dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 121289-23-4
p-methoxybenzyloxyacetaldehyde

: 1-(2-{[(tert-butyldimethylsilanyl)oxy]methyl}allyl)tetrahydrothiophenium tetrafluoroborate

: 288097-98-3
tert-butyl-{2-[3-(4-methoxy-benzyloxymethyl)-oxiran-2-yl]-allyloxy}-dimethylsilane

Guidance literature:: 1-(2-{[(tert-butyldimethylsilanyl)oxy]methyl}allyl)tetrahydrothiophenium tetrafluoroborate; With tert.-butyl lithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.25h;

p-methoxybenzyloxyacetaldehyde; In tetrahydrofuran; hexane; at -78 - 20 ℃; Further stages.;
DOI:10.1021/ol0061236

Reference yield: 98.0%

: 3406-02-8
bis(phenylsulfonyl)methane

: 288097-98-3
tert-butyl-{2-[3-(4-methoxy-benzyloxymethyl)-oxiran-2-yl]-allyloxy}-dimethylsilane

: 288097-99-4
6,6-bis-phenylsulfonyl-4-(tert-butyldimethylsilanyloxymethyl)-1-(4-methoxy-benzyloxy)-hex-3-en-2-ol

Guidance literature:: With 1,2-bis-(diphenylphosphino)ethane; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 20 ℃; for 14h;
DOI:10.1021/ol0061236

Reference yield:

: 288097-98-3
tert-butyl-{2-[3-(4-methoxy-benzyloxymethyl)-oxiran-2-yl]-allyloxy}-dimethylsilane

: (E)-2-(2,2-Bis-benzenesulfonyl-ethyl)-5-(4-methoxy-benzyloxy)-4-(tetrahydro-pyran-2-yloxy)-pent-2-enal

Guidance literature:: Multi-step reaction with 4 steps

1: 98 percent / dppe / Pd(PPh₃)4 / tetrahydrofuran / 14 h / 20 °C

2: 91 percent / pyridinium tosylate / CH₂Cl₂ / 4 h / 0 - 20 °C

3: 95 percent / n-Bu₄NF*3H₂O / tetrahydrofuran / 16 h / 50 °C

4: MnO₂ / CH₂Cl₂ / 3 h / 20 °C

With manganese(IV) oxide; tetrabutyl ammonium fluoride; pyridinium p-toluenesulfonate; 1,2-bis-(diphenylphosphino)ethane; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; dichloromethane; 1: Ring cleavage / 2: Addition / 3: desilylation / 4: Oxidation;
DOI:10.1021/ol0061236