2,3-bis(pentylsulfanyl)-6,7-[3,6-bis(tert-butyldiphenylsilyloxy)benzo]tetrathiafulvalene

Base Information

Chemical Name:2,3-bis(pentylsulfanyl)-6,7-[3,6-bis(tert-butyldiphenylsilyloxy)benzo]tetrathiafulvalene
CAS No.:596815-00-8
Molecular Formula:C₅₂H₆₂O₂S₆Si₂
Molecular Weight:967.63
Hs Code.:

Synonyms:2,3-bis(pentylsulfanyl)-6,7-[3,6-bis(tert-butyldiphenylsilyloxy)benzo]tetrathiafulvalene

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Chemical Property of 2,3-bis(pentylsulfanyl)-6,7-[3,6-bis(tert-butyldiphenylsilyloxy)benzo]tetrathiafulvalene

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Technology Process of 2,3-bis(pentylsulfanyl)-6,7-[3,6-bis(tert-butyldiphenylsilyloxy)benzo]tetrathiafulvalene

There total 7 articles about 2,3-bis(pentylsulfanyl)-6,7-[3,6-bis(tert-butyldiphenylsilyloxy)benzo]tetrathiafulvalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: (4,5-bis-pentylsulfanyl-[1,3]dithiol-2-yl)-phosphonic acid dimethyl ester

: 596815-01-9
4,7-bis(tert-butyldiphenylsilyloxy)-1,3-benzodithiole-2-one

: 596815-00-8
2,3-bis(pentylsulfanyl)-6,7-[3,6-bis(tert-butyldiphenylsilyloxy)benzo]tetrathiafulvalene

Guidance literature:: With n-butyllithium; In tetrahydrofuran; at -78 - 20 ℃;
DOI:10.1002/anie.200250587

Reference yield:

: 53636-07-0
4,7-dihydroxy-1,3-benzodithiole-2-thione

: 596815-00-8
2,3-bis(pentylsulfanyl)-6,7-[3,6-bis(tert-butyldiphenylsilyloxy)benzo]tetrathiafulvalene

Guidance literature:: Multi-step reaction with 3 steps

1: 86 percent / imidazole / dimethylformamide / 20 °C

2: 85 percent / Hg(OAc)2; AcOH / 0.25 h / 20 °C

3: 90 percent / n-BuLi / tetrahydrofuran; hexane / -78 - 20 °C

With 1H-imidazole; n-butyllithium; mercury(II) diacetate; acetic acid; In tetrahydrofuran; hexane; N,N-dimethyl-formamide; 3: Horner-Wadsworth-Emmons reaction;
DOI:10.1021/jo035689f

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 596815-00-8
2,3-bis(pentylsulfanyl)-6,7-[3,6-bis(tert-butyldiphenylsilyloxy)benzo]tetrathiafulvalene

Guidance literature:: Multi-step reaction with 3 steps

1: 86 percent / imidazole / dimethylformamide / 20 °C

2: 85 percent / Hg(OAc)2; AcOH / 0.25 h / 20 °C

3: 90 percent / n-BuLi / tetrahydrofuran; hexane / -78 - 20 °C

With 1H-imidazole; n-butyllithium; mercury(II) diacetate; acetic acid; In tetrahydrofuran; hexane; N,N-dimethyl-formamide; 3: Horner-Wadsworth-Emmons reaction;
DOI:10.1021/jo035689f