((2R,3S,4R,5R)-3,4-Bis-benzyloxy-5-hydroxymethyl-tetrahydro-furan-2-yl)-acetaldehyde

Base Information

Chemical Name:((2R,3S,4R,5R)-3,4-Bis-benzyloxy-5-hydroxymethyl-tetrahydro-furan-2-yl)-acetaldehyde
CAS No.:929113-08-6
Molecular Formula:C₂₁H₂₄O₅
Molecular Weight:356.419
Hs Code.:

Synonyms:((2R,3S,4R,5R)-3,4-Bis-benzyloxy-5-hydroxymethyl-tetrahydro-furan-2-yl)-acetaldehyde

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Chemical Property of ((2R,3S,4R,5R)-3,4-Bis-benzyloxy-5-hydroxymethyl-tetrahydro-furan-2-yl)-acetaldehyde

Chemical Property:

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Technology Process of ((2R,3S,4R,5R)-3,4-Bis-benzyloxy-5-hydroxymethyl-tetrahydro-furan-2-yl)-acetaldehyde

There total 1 articles about ((2R,3S,4R,5R)-3,4-Bis-benzyloxy-5-hydroxymethyl-tetrahydro-furan-2-yl)-acetaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 842130-93-2
((2R,3R,4S,5R)-5-Allyl-3,4-bis-benzyloxy-tetrahydro-furan-2-yl)-methanol

: 929113-08-6
((2R,3S,4R,5R)-3,4-Bis-benzyloxy-5-hydroxymethyl-tetrahydro-furan-2-yl)-acetaldehyde

Guidance literature:: ((2R,3R,4S,5R)-5-Allyl-3,4-bis-benzyloxy-tetrahydro-furan-2-yl)-methanol; With ozone;

With dimethylsulfide;
DOI:10.1021/jo062057v

Reference yield: 59.0%

: 929113-08-6
((2R,3S,4R,5R)-3,4-Bis-benzyloxy-5-hydroxymethyl-tetrahydro-furan-2-yl)-acetaldehyde

: 1730-25-2
allylmagnesium bromide

: 929113-09-7
1-((2R,3S,4R,5R)-3,4-Bis-benzyloxy-5-hydroxymethyl-tetrahydro-furan-2-yl)-pent-4-en-2-ol

Guidance literature:: ((2R,3S,4R,5R)-3,4-Bis-benzyloxy-5-hydroxymethyl-tetrahydro-furan-2-yl)-acetaldehyde; allylmagnesium bromide; In tetrahydrofuran; diethyl ether; for 2h;

With ammonium chloride; In tetrahydrofuran; diethyl ether; water;
DOI:10.1021/jo062057v

Reference yield:

: 929113-08-6
((2R,3S,4R,5R)-3,4-Bis-benzyloxy-5-hydroxymethyl-tetrahydro-furan-2-yl)-acetaldehyde

: 929113-07-5
5-C-(5-azido-2,3-di-O-benzyl-5-deoxy-α-D-ribofuranosyl)-1-penten-4-ol

Guidance literature:: Multi-step reaction with 3 steps

1.1: diethyl ether; tetrahydrofuran / 2 h

1.2: 59 percent / NH₄Cl / diethyl ether; tetrahydrofuran; H₂O

2.1: pyridine / CH₂Cl₂ / 48 h / 4 °C

3.1: 60 mg / NaN₃ / dimethylformamide / 4 h / 80 °C

With pyridine; sodium azide; In tetrahydrofuran; diethyl ether; dichloromethane; N,N-dimethyl-formamide; 1.1: Grignard reaction;
DOI:10.1021/jo062057v