1-(4-hexyloxyphenyl)-4-[4-(6-hydroxyhexyloxy)phenyl]-1,3-butadiyne

Base Information

Chemical Name:1-(4-hexyloxyphenyl)-4-[4-(6-hydroxyhexyloxy)phenyl]-1,3-butadiyne
CAS No.:1388811-41-3
Molecular Formula:C₃₂H₃₈O₄
Molecular Weight:486.651
Hs Code.:

Synonyms:1-(4-hexyloxyphenyl)-4-[4-(6-hydroxyhexyloxy)phenyl]-1,3-butadiyne

Suppliers and Price of 1-(4-hexyloxyphenyl)-4-[4-(6-hydroxyhexyloxy)phenyl]-1,3-butadiyne

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-(4-hexyloxyphenyl)-4-[4-(6-hydroxyhexyloxy)phenyl]-1,3-butadiyne

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1-(4-hexyloxyphenyl)-4-[4-(6-hydroxyhexyloxy)phenyl]-1,3-butadiyne

There total 10 articles about 1-(4-hexyloxyphenyl)-4-[4-(6-hydroxyhexyloxy)phenyl]-1,3-butadiyne which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 1388811-40-2
C₂₈H₃₄O₃

: 920-46-7,26937-45-1
Methacryloyl chloride

: 1388811-41-3
1-(4-hexyloxyphenyl)-4-[4-(6-hydroxyhexyloxy)phenyl]-1,3-butadiyne

Guidance literature:: With triethylamine; In dichloromethane; at 20 ℃; for 7h;
DOI:10.1039/c2jm32489j

Reference yield:

: 1388811-38-8
4-(2,2-dibromoethenyl)-1-hexyloxybenzene

: 1388811-41-3
1-(4-hexyloxyphenyl)-4-[4-(6-hydroxyhexyloxy)phenyl]-1,3-butadiyne

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C

1.2: 0.75 h / 20 °C

1.3: 48 h / 0 °C

2.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 24 h / 20 °C

3.1: triethylamine / dichloromethane / 7 h / 20 °C

With n-butyllithium; tetrabutyl ammonium fluoride; triethylamine; In tetrahydrofuran; hexane; dichloromethane; 1.1: Negishi cross-coupling reaction / 1.2: Negishi coupling reaction / 1.3: Negishi coupling reaction;
DOI:10.1039/c2jm32489j

Reference yield:

: 1388811-39-9
2-bromo-1-(4-hexyloxyphenyl)-4-[4-(6-tert-butyldimethylsiloxyhexyloxy)phenyl]-1-(Z)butene-3yne

: 1388811-41-3
1-(4-hexyloxyphenyl)-4-[4-(6-hydroxyhexyloxy)phenyl]-1,3-butadiyne

Guidance literature:: Multi-step reaction with 2 steps

1: tetrabutyl ammonium fluoride / tetrahydrofuran / 24 h / 20 °C

2: triethylamine / dichloromethane / 7 h / 20 °C

With tetrabutyl ammonium fluoride; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1039/c2jm32489j