(2S,4R,5R)-4-O-benzyl-6-O-benzoyl-2-O-(tert-butyldimethylsilyl)-3,3-difluorohexane-1,2,4,5,6-pentol

Base Information

Chemical Name:(2S,4R,5R)-4-O-benzyl-6-O-benzoyl-2-O-(tert-butyldimethylsilyl)-3,3-difluorohexane-1,2,4,5,6-pentol
CAS No.:1015418-13-9
Molecular Formula:C₂₆H₃₆F₂O₆Si
Molecular Weight:510.651
Hs Code.:

Synonyms:(2S,4R,5R)-4-O-benzyl-6-O-benzoyl-2-O-(tert-butyldimethylsilyl)-3,3-difluorohexane-1,2,4,5,6-pentol

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Chemical Property of (2S,4R,5R)-4-O-benzyl-6-O-benzoyl-2-O-(tert-butyldimethylsilyl)-3,3-difluorohexane-1,2,4,5,6-pentol

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Technology Process of (2S,4R,5R)-4-O-benzyl-6-O-benzoyl-2-O-(tert-butyldimethylsilyl)-3,3-difluorohexane-1,2,4,5,6-pentol

There total 1 articles about (2S,4R,5R)-4-O-benzyl-6-O-benzoyl-2-O-(tert-butyldimethylsilyl)-3,3-difluorohexane-1,2,4,5,6-pentol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1015418-08-2
C₃₂H₅₀O₆F₂Si₂

: 1015418-13-9
(2S,4R,5R)-4-O-benzyl-6-O-benzoyl-2-O-(tert-butyldimethylsilyl)-3,3-difluorohexane-1,2,4,5,6-pentol

Guidance literature:: With toluene-4-sulfonic acid; In methanol; at 0 ℃; for 2h;
DOI:10.1016/j.jfluchem.2007.01.007

Reference yield: 72.0%

: 1015418-13-9
(2S,4R,5R)-4-O-benzyl-6-O-benzoyl-2-O-(tert-butyldimethylsilyl)-3,3-difluorohexane-1,2,4,5,6-pentol

: 1015418-15-1
C₂₆H₃₂O₆F₂Si

Guidance literature:: With 2,2,6,6-tetramethyl-piperidine-N-oxyl; trichloroisocyanuric acid; In dichloromethane; at 20 ℃; for 0.25h;
DOI:10.1016/j.jfluchem.2007.01.007

Reference yield:

: 1015418-13-9
(2S,4R,5R)-4-O-benzyl-6-O-benzoyl-2-O-(tert-butyldimethylsilyl)-3,3-difluorohexane-1,2,4,5,6-pentol

: 4-O-benzyl-2-O-(tert-butyldimethylsilyloxy)-3-deoxy-3,3-difluoro-D-ribohexose

Guidance literature:: Multi-step reaction with 2 steps

1: 72 percent / 2,2,6,6-tetramethyl-1-piperidinyloxy; trichloroisocyanuric acid / CH₂Cl₂ / 0.25 h / 20 °C

2: 73 percent / DIBAL-H / CH₂Cl₂; cyclohexane / 1 h / -78 °C

With 2,2,6,6-tetramethyl-piperidine-N-oxyl; trichloroisocyanuric acid; diisobutylaluminium hydride; In dichloromethane; cyclohexane;
DOI:10.1016/j.jfluchem.2007.01.007