3-deoxy-1,2-O-isopropylidene-5-O-p-tolylsulfonyl-β-L-threo-pentofuranose

Base Information

Chemical Name:3-deoxy-1,2-O-isopropylidene-5-O-p-tolylsulfonyl-β-L-threo-pentofuranose
CAS No.:41107-52-2
Molecular Formula:C₁₅H₂₀O₆S
Molecular Weight:328.386
Hs Code.:

Synonyms:3-deoxy-1,2-O-isopropylidene-5-O-p-tolylsulfonyl-β-L-threo-pentofuranose

Suppliers and Price of 3-deoxy-1,2-O-isopropylidene-5-O-p-tolylsulfonyl-β-L-threo-pentofuranose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3-deoxy-1,2-O-isopropylidene-5-O-p-tolylsulfonyl-β-L-threo-pentofuranose

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3-deoxy-1,2-O-isopropylidene-5-O-p-tolylsulfonyl-β-L-threo-pentofuranose

There total 14 articles about 3-deoxy-1,2-O-isopropylidene-5-O-p-tolylsulfonyl-β-L-threo-pentofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 14260-66-3
((3αR,5S,6αR)-2,2-dimethyl-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl)methanol

: 98-59-9
p-toluenesulfonyl chloride

: 41107-52-2
3-deoxy-1,2-O-isopropylidene-5-O-p-tolylsulfonyl-β-L-threo-pentofuranose

Guidance literature:: With triethylamine; In dichloromethane; at 20 ℃;
DOI:10.1021/ol020112q

Reference yield:

: C₉H₁₆O₄

: 98-59-9
p-toluenesulfonyl chloride

: 41107-52-2
3-deoxy-1,2-O-isopropylidene-5-O-p-tolylsulfonyl-β-L-threo-pentofuranose

Guidance literature:: With triethylamine; In dichloromethane;
DOI:10.1016/j.carres.2013.07.017

Reference yield:

: 103763-14-0
(3aR,5S,6S,6aR)-5-{[(tert-butyldiphenylsilyl)oxy]methyl}-2,2-dimethyltetrahydro-2H-furo[2,3-d][1,3]dioxol-6-ol

: 41107-52-2
3-deoxy-1,2-O-isopropylidene-5-O-p-tolylsulfonyl-β-L-threo-pentofuranose

Guidance literature:: Multi-step reaction with 4 steps

1: 98 percent / NaH / tetrahydrofuran / 2 h / 20 °C

2: 84 percent / Bu₃SnH; AIBN / toluene / 5 h / Heating

3: 81 percent / 1M Bu₄NF / tetrahydrofuran / 4 h / 20 °C

4: 92 percent / Et₃N / CH₂Cl₂ / 20 °C

With 2,2'-azobis(isobutyronitrile); tetrabutyl ammonium fluoride; tri-n-butyl-tin hydride; sodium hydride; triethylamine; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1021/ol020112q