(+)-(4S)-3-(Benzyloxycarbonyl)-4-<3-(ethoxycarbonyl)-2-oxo-3-(triphenylphosphoranylidene)propyl>-1,3-oxazolidin-5-one

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Chemical Name:(+)-(4S)-3-(Benzyloxycarbonyl)-4-<3-(ethoxycarbonyl)-2-oxo-3-(triphenylphosphoranylidene)propyl>-1,3-oxazolidin-5-one
CAS No.:167280-62-8
Molecular Formula:C₃₅H₃₂NO₇P
Molecular Weight:609.615
Hs Code.:
Mol file:167280-62-8.mol

Synonyms:(+)-(4S)-3-(Benzyloxycarbonyl)-4-<3-(ethoxycarbonyl)-2-oxo-3-(triphenylphosphoranylidene)propyl>-1,3-oxazolidin-5-one

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Chemical Property of (+)-(4S)-3-(Benzyloxycarbonyl)-4-<3-(ethoxycarbonyl)-2-oxo-3-(triphenylphosphoranylidene)propyl>-1,3-oxazolidin-5-one Edit

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Technology Process of (+)-(4S)-3-(Benzyloxycarbonyl)-4-<3-(ethoxycarbonyl)-2-oxo-3-(triphenylphosphoranylidene)propyl>-1,3-oxazolidin-5-one

There total 2 articles about (+)-(4S)-3-(Benzyloxycarbonyl)-4-<3-(ethoxycarbonyl)-2-oxo-3-(triphenylphosphoranylidene)propyl>-1,3-oxazolidin-5-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 111197-44-5
(4S)-4-(Chloroformyl)methyl-3-[(phenylmethoxy)carbonyl]oxazolidin-5-one

: 1099-45-2
ethyl (triphenylphosphoranylidene)acetate

: 167280-62-8
(+)-(4S)-3-(Benzyloxycarbonyl)-4-<3-(ethoxycarbonyl)-2-oxo-3-(triphenylphosphoranylidene)propyl>-1,3-oxazolidin-5-one

Guidance literature:: In dichloromethane; 1.) 0 deg C, 30 min, 2.) 20 deg C, 30 min;
DOI:10.1021/jo00110a026

Reference yield:

: 23632-66-8
(4S)-3-benzyloxycarbonyl-4-carboxymethyl-1,3-oxazolidin-5-one

: 167280-62-8
(+)-(4S)-3-(Benzyloxycarbonyl)-4-<3-(ethoxycarbonyl)-2-oxo-3-(triphenylphosphoranylidene)propyl>-1,3-oxazolidin-5-one

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / (COCl)2, DMF / CH₂Cl₂ / 1.) 0 deg C, 2 h, 2.) 20 deg C, 16 h

2: 100 percent / CH₂Cl₂ / 1.) 0 deg C, 30 min, 2.) 20 deg C, 30 min

With oxalyl dichloride; N,N-dimethyl-formamide; In dichloromethane;
DOI:10.1021/jo00110a026