2-Isocyanatobicyclo[2.2.1]heptane

Base Information

Chemical Name:2-Isocyanatobicyclo[2.2.1]heptane
CAS No.:14370-47-9
Molecular Formula:C₈H₁₁NO
Molecular Weight:137.181
Hs Code.:
European Community (EC) Number:823-019-3

Synonyms:2-isocyanatobicyclo[2.2.1]heptane;14370-47-9;2-norbornyl isocyanate;SCHEMBL7785952;HQTBWWAAVGMMRU-UHFFFAOYSA-N;AKOS010621660;bicyclo[2.2.1]heptane-2-yl isocyanate;EN300-129813

Suppliers and Price of 2-Isocyanatobicyclo[2.2.1]heptane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of 2-Isocyanatobicyclo[2.2.1]heptane

Chemical Property:

XLogP3:2.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:137.084063974
Heavy Atom Count:10
Complexity:184

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1CC2CC1CC2N=C=O

Technology Process of 2-Isocyanatobicyclo[2.2.1]heptane

There total 5 articles about 2-Isocyanatobicyclo[2.2.1]heptane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 934-28-1,934-29-2,2566-58-7,2566-59-8,61967-05-3,79026-23-6,117894-69-6,130793-99-6,824-62-4
norbornane-2-carboxylic acid

: 14370-47-9,344585-18-8
bicyclo[2.2.1]heptane-2-yl isocyanate

Guidance literature:: With diphenyl phosphoryl azide; triethylamine; In toluene; at 110 ℃; for 1h; Reflux;
DOI:10.1134/S1070428020110020

Reference yield:

: 1118-02-1
trimethylsilyl isocyanate

: 279-23-2
norbornene

: 14370-47-9,57561-64-5,344585-18-8
endo-2-isocyanatonorbornane

: 344585-18-8
exo-2-isocyanatonorbornane

Guidance literature:: With iodosylbenzene; Mn(5,10,15,20-tetramesitylporphinato)F; silver fluoride; In ethyl acetate; at 20 ℃; Overall yield = 58 %Chromat.; Inert atmosphere; Schlenk technique;
DOI:10.1021/jacs.7b07658

Reference yield:

: 76649-94-0
bicyclo[2.2.1]heptane-2-carboxamide

: 14370-47-9,344585-18-8
bicyclo[2.2.1]heptane-2-yl isocyanate

Guidance literature:: With sodium hydroxide; bromine; PTC; Yield given. Multistep reaction; CH₂Cl₂, H₂O, 25 deg C, 15 min.;
DOI:10.1016/0040-4039(80)80008-6