(2R,3S,4S,5S,6R)-3-Benzyloxy-4-methyl-6-phenyl-5-vinyl-hexane-1,2,6-triol

Base Information

Chemical Name:(2R,3S,4S,5S,6R)-3-Benzyloxy-4-methyl-6-phenyl-5-vinyl-hexane-1,2,6-triol
CAS No.:133604-49-6
Molecular Formula:C₂₂H₂₈O₄
Molecular Weight:356.462
Hs Code.:

Synonyms:(2R,3S,4S,5S,6R)-3-Benzyloxy-4-methyl-6-phenyl-5-vinyl-hexane-1,2,6-triol

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Chemical Property of (2R,3S,4S,5S,6R)-3-Benzyloxy-4-methyl-6-phenyl-5-vinyl-hexane-1,2,6-triol

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Technology Process of (2R,3S,4S,5S,6R)-3-Benzyloxy-4-methyl-6-phenyl-5-vinyl-hexane-1,2,6-triol

There total 1 articles about (2R,3S,4S,5S,6R)-3-Benzyloxy-4-methyl-6-phenyl-5-vinyl-hexane-1,2,6-triol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 133604-08-7
(2R,3S,4S,5S,6R)-3-O-benzyl-1,2-O-isopropylidene-4-methyl-6-phenyl-5-vinylhexane-1,2,3,6-tetrol

: 133604-49-6
(2R,3S,4S,5S,6R)-3-Benzyloxy-4-methyl-6-phenyl-5-vinyl-hexane-1,2,6-triol

Guidance literature:: With toluene-4-sulfonic acid; In methanol; at 22 ℃; for 24h;
DOI:10.1021/ja00011a025

Reference yield:

: 133604-49-6
(2R,3S,4S,5S,6R)-3-Benzyloxy-4-methyl-6-phenyl-5-vinyl-hexane-1,2,6-triol

: 133604-50-9
(2R,3S,4S,5S,6R)-4-Methyl-6-phenyl-5-vinyl-hexane-1,2,3,6-tetraol

Guidance literature:: With ammonia; sodium; In tetrahydrofuran; at -40 ℃; for 0.5h; Yield given;
DOI:10.1021/ja00011a025

Reference yield:

: 133604-49-6
(2R,3S,4S,5S,6R)-3-Benzyloxy-4-methyl-6-phenyl-5-vinyl-hexane-1,2,6-triol

: 133604-47-4
(1R,2S,3S)-3-Methyl-1-phenyl-2-vinyl-butane-1,4-diol

Guidance literature:: Multi-step reaction with 2 steps

1: Na, NH₃ / tetrahydrofuran / 0.5 h / -40 °C

2: 1.) H₅IO₆, 2.) LiAlH₄ / 1.) THF, 22 deg C, 20 min, 2.) THF, 22 deg C, 24 h

With lithium aluminium tetrahydride; ammonia; sodium; periodic acid; In tetrahydrofuran;
DOI:10.1021/ja00011a025