C₄₆H₆₇IO₃Si₃

Base Information

Chemical Name:C₄₆H₆₇IO₃Si₃
CAS No.:860438-09-1
Molecular Formula:C₄₆H₆₇IO₃Si₃
Molecular Weight:879.197
Hs Code.:

C<sub>46</sub>H<sub>67</sub>IO<sub>3</sub>Si<sub>3</sub>

Synonyms:C₄₆H₆₇IO₃Si₃

Suppliers and Price of C₄₆H₆₇IO₃Si₃

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of C₄₆H₆₇IO₃Si₃

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of C₄₆H₆₇IO₃Si₃

There total 9 articles about C₄₆H₆₇IO₃Si₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 860437-87-2
8-(tert-butyl-dimethyl-silanyloxy)-3,7-bis-(tert-butyl-diphenyl-silanyloxy)-octan-1-ol

: 860438-09-1
C₄₆H₆₇IO₃Si₃

Guidance literature:: With 1H-imidazole; iodine; triphenylphosphine; In tetrahydrofuran; at 20 ℃; for 1h;
DOI:10.1021/ol0511833

Reference yield:

: 4-(tert-butyl-dimethyl-silanyloxy)-3-(tert-butyl-diphenyl-silanyloxy)-butyric acid methyl ester

: 860438-09-1
C₄₆H₆₇IO₃Si₃

Guidance literature:: Multi-step reaction with 6 steps

1.1: 86 percent / CSA / CH₂Cl₂; methanol / 6 h / -10 °C

2.1: 82 percent / Dess-Martin reagent; pyridine / CH₂Cl₂ / 4 h / 20 °C

3.1: 72 percent / KHMDS / tetrahydrofuran; toluene / -78 - 20 °C

4.1: 91 percent / H₂ / Pd/C / ethyl acetate / 48 h

5.1: DibalH / CH₂Cl₂; hexane / 6 h / -78 °C

5.2: 89 percent / NaBH₄ / tetrahydrofuran; methanol / 2 h / 0 °C

6.1: 100 percent / imidazole; PPh₃; I₂ / tetrahydrofuran / 1 h / 20 °C

With pyridine; 1H-imidazole; camphor-10-sulfonic acid; hydrogen; iodine; potassium hexamethylsilazane; diisobutylaluminium hydride; Dess-Martin periodane; triphenylphosphine; palladium on activated charcoal; In tetrahydrofuran; methanol; hexane; dichloromethane; ethyl acetate; toluene; 3.1: Julia-Kocienski olefination;
DOI:10.1021/ol0511833

Reference yield:

: 860437-82-7
3-(tert-butyl-diphenyl-silanyloxy)-4-oxo-butyric acid methyl ester

: 860438-09-1
C₄₆H₆₇IO₃Si₃

Guidance literature:: Multi-step reaction with 4 steps

1.1: 72 percent / KHMDS / tetrahydrofuran; toluene / -78 - 20 °C

2.1: 91 percent / H₂ / Pd/C / ethyl acetate / 48 h

3.1: DibalH / CH₂Cl₂; hexane / 6 h / -78 °C

3.2: 89 percent / NaBH₄ / tetrahydrofuran; methanol / 2 h / 0 °C

4.1: 100 percent / imidazole; PPh₃; I₂ / tetrahydrofuran / 1 h / 20 °C

With 1H-imidazole; hydrogen; iodine; potassium hexamethylsilazane; diisobutylaluminium hydride; triphenylphosphine; palladium on activated charcoal; In tetrahydrofuran; hexane; dichloromethane; ethyl acetate; toluene; 1.1: Julia-Kocienski olefination;
DOI:10.1021/ol0511833