[PtMe(N,N'-(1,2-dimethyl-1,2-ethanediylidene)bis(2,6-diisopropylaniline)))(ethylene)]

Base Information

• Chemical Name: [PtMe(N,N'-(1,2-dimethyl-1,2-ethanediylidene)bis(2,6-diisopropylaniline)))(ethylene)]
• CAS No.: 691894-16-3
• Molecular Formula: C₃₁H₄₆N₂Pt
• Molecular Weight: 641.8
• Mol file: 691894-16-3.mol

Synonyms:[PtMe(N,N'-(1,2-dimethyl-1,2-ethanediylidene)bis(2,6-diisopropylaniline)))(ethylene)]

Chemical Property of [PtMe(N,N'-(1,2-dimethyl-1,2-ethanediylidene)bis(2,6-diisopropylaniline)))(ethylene)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [PtMe(N,N'-(1,2-dimethyl-1,2-ethanediylidene)bis(2,6-diisopropylaniline)))(ethylene)]

There total 1 articles about [PtMe(N,N'-(1,2-dimethyl-1,2-ethanediylidene)bis(2,6-diisopropylaniline)))(ethylene)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

[PtMe(N,N'-bis(2,6-diisopropylphenyl)butane-2,3-diimine)(ethylene)]BF4 (199284-74-7) → [PtMe(N,N'-(1,2-dimethyl-1,2-ethanediylidene)bis(2,6-diisopropylaniline)))(ethylene)] (691894-16-3)

Guidance literature:

With KOH; In methanol; soln. of KOH in methanol was added to stirred suspn. of Pt complex in methanol kept in ice bath; mixt. was stirred for 15 min; septd.; washed (cold methanol); dried (vac.); elem. anal.;

DOI:10.1021/om049968k

Reference yield:

tetrafluoroboric acid + [PtMe(N,N'-(1,2-dimethyl-1,2-ethanediylidene)bis(2,6-diisopropylaniline)))(ethylene)] (691894-16-3) → [PtMe(N,N'-bis(2,6-diisopropylphenyl)butane-2,3-diimine)(ethylene)]BF4 (199284-74-7)

Guidance literature:

In diethyl ether; chloroform; ethereal HBF4 was added to soln. of Pt complex in CHCl3;

DOI:10.1021/om049968k

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + [PtMe(N,N'-(1,2-dimethyl-1,2-ethanediylidene)bis(2,6-diisopropylaniline)))(ethylene)] (691894-16-3) → [PtCl(Me)(diacetyl bis(2,6-diisopropylphenylimine))] (199284-91-8)

Guidance literature:

In not given; byproducts: C2H4; HCl was added to soln. of Pt complex;

DOI:10.1021/om049968k

upstream raw materials:

[PtMe(N,N'-bis(2,6-diisopropylphenyl)butane-2,3-diimine)(ethylene)]BF₄

Downstream raw materials:

[PtMe(N,N'-bis(2,6-diisopropylphenyl)butane-2,3-diimine)(ethylene)]BF₄

[PtCl(Me)(diacetyl bis(2,6-diisopropylphenylimine))]