6-Benzyloxy-2-naphthylboronic acid

Base Information

Chemical Name:6-Benzyloxy-2-naphthylboronic acid
CAS No.:152915-83-8
Molecular Formula:C17H15BO3
Molecular Weight:278.11
Hs Code.:2931900090
DSSTox Substance ID:DTXSID90383273
Wikidata:Q82174941
Mol file:152915-83-8.mol

Synonyms:152915-83-8;6-Benzyloxy-2-naphthylboronic acid;6-(Benzyloxy)-2-naphthylboronic acid;6-Benzyloxynaphthalene-2-boronic acid;6-(benzyloxy)naphthalen-2-ylboronic acid;(6-phenylmethoxynaphthalen-2-yl)boronic Acid;Boronic acid,B-[6-(phenylmethoxy)-2-naphthalenyl]-;[6-(benzyloxy)naphthalen-2-yl]boronic acid;(6-(Benzyloxy)naphthalen-2-yl)boronic acid;SCHEMBL257567;DTXSID90383273;6-Benzyloxy-2-naphthylboronicacid;CGA91583;MFCD04115402;AKOS004119294;AB19956;BS-27515;CS-0174971;FT-0715065;D71319;A883864

Suppliers and Price of 6-Benzyloxy-2-naphthylboronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
6-Benzyloxynaphthalene-2-boronicAcid
1g
$ 75.00

TRC
6-Benzyloxynaphthalene-2-boronicAcid
100mg
$ 45.00

Matrix Scientific
6-Benzyloxy-2-naphthylboronic acid 95+%
5g
$ 908.00

AOBChem
6-(Benzyloxy)-2-naphthylboronicacid 97%
100g
$ 1608.00

American Custom Chemicals Corporation
6-(BENZYLOXY)-2-NAPHTHYLBORONIC ACID 95.00%
1G
$ 374.85

American Custom Chemicals Corporation
6-(BENZYLOXY)-2-NAPHTHYLBORONIC ACID 95.00%
5G
$ 1517.16

Alichem
6-Benzyloxy-2-naphthylboronicacid
25g
$ 998.00

AK Scientific
6-Benzyloxynaphthalene-2-boronicacid
5g
$ 291.00

Total 23 raw suppliers

Chemical Property of 6-Benzyloxy-2-naphthylboronic acid

Chemical Property:

Vapor Pressure:3.06E-11mmHg at 25°C
Refractive Index:1.655
Boiling Point:510.4 °C at 760 mmHg
Flash Point:262.5 °C
PSA：49.69000
Density:1.24 g/cm³
LogP:2.09860
Storage Temp.:Room temperature.
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:278.1114245
Heavy Atom Count:21
Complexity:317

Purity/Quality:

97% ^*data from raw suppliers

6-Benzyloxynaphthalene-2-boronicAcid ^*data from reagent suppliers

Safty Information:

Pictogram(s): R36/37/38:Irritating to eyes, respiratory system and skin.;
Hazard Codes: Xi:Irritant;
Statements: R36/37/38:Irritating to eyes, respiratory system and skin.;
Safety Statements: S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.; S37/39:Wear suitable g

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B(C1=CC2=C(C=C1)C=C(C=C2)OCC3=CC=CC=C3)(O)O

Technology Process of 6-Benzyloxy-2-naphthylboronic acid

There total 6 articles about 6-Benzyloxy-2-naphthylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: C₂₃H₂₇BO₃

: 152915-83-8
(6-(benzyloxy)naphthalen-2-yl)boronic acid

Guidance literature:: With hydrogenchloride;
DOI:10.1016/j.bmcl.2006.08.025

Reference yield: 65.0%

: 5419-55-6
Triisopropyl borate

: 2234-45-9
6-benzyloxy-2-bromonaphthalene

: 152915-83-8
(6-(benzyloxy)naphthalen-2-yl)boronic acid

Guidance literature:: 6-benzyloxy-2-bromonaphthalene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.166667h;

Triisopropyl borate; In tetrahydrofuran; at -78 ℃; for 1.75h;

With hydrogenchloride; In tetrahydrofuran; water;
DOI:10.1002/chem.201403630

Reference yield:

: 15231-91-1
6-bromo-naphthalen-2-ol

: 152915-83-8
(6-(benzyloxy)naphthalen-2-yl)boronic acid

Guidance literature:: Multi-step reaction with 3 steps

1.1: NaH / dimethylformamide / 1 h / 0 - 20 °C

2.1: BuLi / tetrahydrofuran / -78 °C

2.2: tetrahydrofuran / 16 h / 20 °C

3.1: 81 percent / HCl

With hydrogenchloride; n-butyllithium; sodium hydride; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1016/j.bmcl.2006.08.025