(4R)-4-benzyl-3-<(2R,3S)-2-benzyloxy-3-hydroxy-3-(3,4-methylenedioxyphenyl)propionyl>-2-oxazolidinone

Base Information

Chemical Name:(4R)-4-benzyl-3-<(2R,3S)-2-benzyloxy-3-hydroxy-3-(3,4-methylenedioxyphenyl)propionyl>-2-oxazolidinone
CAS No.:214269-30-4
Molecular Formula:C₂₇H₂₅NO₇
Molecular Weight:475.498
Hs Code.:

Synonyms:(4R)-4-benzyl-3-<(2R,3S)-2-benzyloxy-3-hydroxy-3-(3,4-methylenedioxyphenyl)propionyl>-2-oxazolidinone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (4R)-4-benzyl-3-<(2R,3S)-2-benzyloxy-3-hydroxy-3-(3,4-methylenedioxyphenyl)propionyl>-2-oxazolidinone

Chemical Property:

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Technology Process of (4R)-4-benzyl-3-<(2R,3S)-2-benzyloxy-3-hydroxy-3-(3,4-methylenedioxyphenyl)propionyl>-2-oxazolidinone

There total 1 articles about (4R)-4-benzyl-3-<(2R,3S)-2-benzyloxy-3-hydroxy-3-(3,4-methylenedioxyphenyl)propionyl>-2-oxazolidinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 120-57-0,30024-74-9
piperonal

: 40217-17-2,90719-32-7,120574-96-1,102029-44-7
(R)-4-(phenylmethyl)-2-oxazolidinone

: 214269-30-4
(4R)-4-benzyl-3-<(2R,3S)-2-benzyloxy-3-hydroxy-3-(3,4-methylenedioxyphenyl)propionyl>-2-oxazolidinone

Guidance literature:: With di-n-butylboryl trifluoromethanesulfonate; triethylamine; Yield given; Multistep reaction; 1.) CH₂Cl₂, -78 deg C, 2 h, 2.) CH₂Cl₂, -78 deg C, 1 h, then 0 deg C, 1 h;
DOI:10.1271/bbb.62.1550

Reference yield: 99.0%

: 214269-30-4
(4R)-4-benzyl-3-<(2R,3S)-2-benzyloxy-3-hydroxy-3-(3,4-methylenedioxyphenyl)propionyl>-2-oxazolidinone

: 214269-31-5
(1S,2S)-2-benzyloxy-1-(3,4-methylenedioxyphenyl)-1,3-propanediol

Guidance literature:: With lithium borohydride; In tetrahydrofuran; methanol; for 24h; Ambient temperature;
DOI:10.1271/bbb.62.1550

Reference yield:

: 214269-30-4
(4R)-4-benzyl-3-<(2R,3S)-2-benzyloxy-3-hydroxy-3-(3,4-methylenedioxyphenyl)propionyl>-2-oxazolidinone

: (1S,2R)-2-<(2-hydroxy-4-methoxyphenyl)oxy>-1-(3,4-methylenedioxyphenyl)-1,3-propanediol

Guidance literature:: Multi-step reaction with 5 steps

1: 99 percent / LiBH₄ / tetrahydrofuran; methanol / 24 h / Ambient temperature

2: 92 percent / pyridinium p-toluenesulfonate / CH₂Cl₂ / 24 h / Ambient temperature

3: 96 percent / H₂ / Pd/C / ethyl acetate / Ambient temperature

4: 54 percent / PPh₃, diethyl azodicarboxylate / benzene; toluene / 24 h / Heating

5: 90 percent / p-toluenesulfonic acid / methanol / 2 h / Ambient temperature

With lithium borohydride; hydrogen; pyridinium p-toluenesulfonate; toluene-4-sulfonic acid; triphenylphosphine; diethylazodicarboxylate; palladium on activated charcoal; In tetrahydrofuran; methanol; dichloromethane; ethyl acetate; toluene; benzene;
DOI:10.1271/bbb.62.1550