4-triethylsilanylcyclohex-3-ene-1,1-dicarboxylic acid diisopropyl ester

Base Information

Chemical Name:4-triethylsilanylcyclohex-3-ene-1,1-dicarboxylic acid diisopropyl ester
CAS No.:1464071-68-8
Molecular Formula:C₂₀H₃₆O₄Si
Molecular Weight:368.589
Hs Code.:

Synonyms:4-triethylsilanylcyclohex-3-ene-1,1-dicarboxylic acid diisopropyl ester

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Chemical Property of 4-triethylsilanylcyclohex-3-ene-1,1-dicarboxylic acid diisopropyl ester

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Technology Process of 4-triethylsilanylcyclohex-3-ene-1,1-dicarboxylic acid diisopropyl ester

There total 5 articles about 4-triethylsilanylcyclohex-3-ene-1,1-dicarboxylic acid diisopropyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: 1464071-66-6
2-(5-acetoxy-3-triethylsilanylpent-3-enyl)malonic acid diisopropyl ester

: 1464071-68-8
4-triethylsilanylcyclohex-3-ene-1,1-dicarboxylic acid diisopropyl ester

Guidance literature:: 2-(5-acetoxy-3-triethylsilanylpent-3-enyl)malonic acid diisopropyl ester; With sodium hydride; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;

With palladium diacetate; triphenylphosphine; In tetrahydrofuran; at 20 ℃; for 2h; Inert atmosphere; Reflux;
DOI:10.1016/j.tet.2013.08.080

Reference yield:

: 1464071-58-6
2-(5-hydroxy-3-triethylsilanylpent-3-enyl)malonic acid dimethyl ester

: 1464071-68-8
4-triethylsilanylcyclohex-3-ene-1,1-dicarboxylic acid diisopropyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: titanium(IV) isopropylate / 80 °C

2.1: triethylamine / dichloromethane / 0 - 20 °C

3.1: sodium hydride / tetrahydrofuran / 0 - 20 °C / Inert atmosphere

3.2: 2 h / 20 °C / Inert atmosphere; Reflux

With titanium(IV) isopropylate; sodium hydride; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1016/j.tet.2013.08.080

Reference yield:

: C₂₀H₃₈O₅Si

: 1464071-68-8
4-triethylsilanylcyclohex-3-ene-1,1-dicarboxylic acid diisopropyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: triethylamine / dichloromethane / 0 - 20 °C

2.1: sodium hydride / tetrahydrofuran / 0 - 20 °C / Inert atmosphere

2.2: 2 h / 20 °C / Inert atmosphere; Reflux

With sodium hydride; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1016/j.tet.2013.08.080