Propane,1,3-diazido-2-(azidomethyl)-2-methyl-

Base Information

• Chemical Name: Propane,1,3-diazido-2-(azidomethyl)-2-methyl-
• CAS No.: 31044-86-7
• Molecular Formula: C5H9 N9
• Molecular Weight: 195.19
• Mol file: 31044-86-7.mol

Synonyms:1,1,1-Tris(azidomethyl)ethane;1,3-Diazido-2-azidomethyl-2-methylpropane

Chemical Property of Propane,1,3-diazido-2-(azidomethyl)-2-methyl-

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Safety Statements: Potentially explosive reaction with hydrogen + palladium catalyst. When heated to decomposi"> x. See also AZIDES." target="_blank">Potentially explosive reaction with hydrogen + palladium catalyst. When heated to decomposi

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Propane,1,3-diazido-2-(azidomethyl)-2-methyl-

There total 4 articles about Propane,1,3-diazido-2-(azidomethyl)-2-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethylidynetris(methyl) tris(benzenesulfonate) (31044-85-6) → α,α,α-tris(azidomethyl)ethane (31044-86-7)

Guidance literature:

With sodium azide; In diethylene glycol; at 135 ℃; for 16h;

DOI:10.1021/jo00819a031

Reference yield:

2-(hydroxymethyl)-2-methylpropane-1,3-diol (77-85-0) → α,α,α-tris(azidomethyl)ethane (31044-86-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 90 percent / pyridine / 0 - 20 °C

2: sodium azide / dimethylsulfoxide / 4 h / 90 °C

With pyridine; sodium azide; In dimethyl sulfoxide;

DOI:10.1016/j.tet.2007.05.022

Reference yield:

2-methyl-2-((tosyloxy)methyl)propane-1,3-diyl bis(4-methylbenzenesulfonate) (2387-43-1) → α,α,α-tris(azidomethyl)ethane (31044-86-7)

Guidance literature:

With sodium azide; In dimethyl sulfoxide; at 90 ℃; for 4h;

DOI:10.1016/j.tet.2007.05.022

upstream raw materials:

ethylidynetris(methyl) tris(benzenesulfonate)

2-methyl-2-((tosyloxy)methyl)propane-1,3-diyl bis(4-methylbenzenesulfonate)

2-(hydroxymethyl)-2-methylpropane-1,3-diol

Downstream raw materials:

1,1,1-Tris(aminomethyl)ethane

α,α,α-tris[((triphenylphosphoranylidene)amino)methyl]ethane