(-)-2,2-dimethyl-3-(2-benzyloxyethyl)-1-(2-hydroxyethyl)-cis-cyclopropane

Base Information

Chemical Name:(-)-2,2-dimethyl-3-(2-benzyloxyethyl)-1-(2-hydroxyethyl)-cis-cyclopropane
CAS No.:91318-97-7
Molecular Formula:C₁₆H₂₄O₂
Molecular Weight:248.365
Hs Code.:

Synonyms:(-)-2,2-dimethyl-3-(2-benzyloxyethyl)-1-(2-hydroxyethyl)-cis-cyclopropane

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Chemical Property of (-)-2,2-dimethyl-3-(2-benzyloxyethyl)-1-(2-hydroxyethyl)-cis-cyclopropane

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Technology Process of (-)-2,2-dimethyl-3-(2-benzyloxyethyl)-1-(2-hydroxyethyl)-cis-cyclopropane

There total 7 articles about (-)-2,2-dimethyl-3-(2-benzyloxyethyl)-1-(2-hydroxyethyl)-cis-cyclopropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 91318-96-6
2,2-dimethyl-1-(2-benzyloxyethyl)-3-(2-tetrahydropyranyloxyethyl)-cis-cyclopropane

: 91318-97-7
(-)-2,2-dimethyl-3-(2-benzyloxyethyl)-1-(2-hydroxyethyl)-cis-cyclopropane

Guidance literature:: With pyridinium p-toluenesulfonate; In ethanol; at 50 ℃; for 2h;

Reference yield:

: 32543-59-2
2-((1R,3S)-2,2-dimethyl-3-(2-oxopropyl)cyclopropyl)acetaldehyde

: 91318-97-7
(-)-2,2-dimethyl-3-(2-benzyloxyethyl)-1-(2-hydroxyethyl)-cis-cyclopropane

Guidance literature:: Multi-step reaction with 7 steps

1: 1) lithium tri-tert-butoxyaluminum hydride; 2) NH₄Cl / 1) THF, 50 deg C, 2 h

2: 99 percent / pyridinium p-toluenesulfonate / CH₂Cl₂ / Ambient temperature

4: diethyl ether

5: 98 percent / LiAlH₄ / diethyl ether / 0.67 h / 0 °C

6: 1) 50 percent sodium hydride; 2) tetra-n-butylammonium iodide / 1) mineral oil, THF, RT, 1 h; 2) RT, 9 h, THF, mineral oil

7: 92 percent / PPTS / ethanol / 2 h / 50 °C

With lithium aluminium tetrahydride; lithium tri(t-butoxy)aluminum hydride; pyridinium p-toluenesulfonate; tetra-(n-butyl)ammonium iodide; sodium hydride; ammonium chloride; In diethyl ether; ethanol; dichloromethane;

Reference yield:

: 82425-89-6
(-)-2-<(1R,3S)-2,2-Dimethyl-3-(2-oxopropyl)cyclopropyl>ethanol

: 91318-97-7
(-)-2,2-dimethyl-3-(2-benzyloxyethyl)-1-(2-hydroxyethyl)-cis-cyclopropane

Guidance literature:: Multi-step reaction with 6 steps

1: 99 percent / pyridinium p-toluenesulfonate / CH₂Cl₂ / Ambient temperature

3: diethyl ether

4: 98 percent / LiAlH₄ / diethyl ether / 0.67 h / 0 °C

5: 1) 50 percent sodium hydride; 2) tetra-n-butylammonium iodide / 1) mineral oil, THF, RT, 1 h; 2) RT, 9 h, THF, mineral oil

6: 92 percent / PPTS / ethanol / 2 h / 50 °C

With lithium aluminium tetrahydride; pyridinium p-toluenesulfonate; tetra-(n-butyl)ammonium iodide; sodium hydride; In diethyl ether; ethanol; dichloromethane;