p-tolyl 5-O-p-methoxybenzyl-1-thio-2,3-O-xylylene-α-D-arabinofuranoside

Base Information

Chemical Name:p-tolyl 5-O-p-methoxybenzyl-1-thio-2,3-O-xylylene-α-D-arabinofuranoside
CAS No.:1239914-71-6
Molecular Formula:C₂₈H₃₀O₅S
Molecular Weight:478.609
Hs Code.:

Synonyms:p-tolyl 5-O-p-methoxybenzyl-1-thio-2,3-O-xylylene-α-D-arabinofuranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of p-tolyl 5-O-p-methoxybenzyl-1-thio-2,3-O-xylylene-α-D-arabinofuranoside

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Technology Process of p-tolyl 5-O-p-methoxybenzyl-1-thio-2,3-O-xylylene-α-D-arabinofuranoside

There total 1 articles about p-tolyl 5-O-p-methoxybenzyl-1-thio-2,3-O-xylylene-α-D-arabinofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 1239914-68-1
p-tolyl 1-thio-2,3-O-xylylene-α-D-arabinofuranoside

: 824-94-2
p-methoxybenzyl chloride

: 1239914-71-6
p-tolyl 5-O-p-methoxybenzyl-1-thio-2,3-O-xylylene-α-D-arabinofuranoside

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1021/ol101520q

Reference yield: 80.0%

: 1239914-71-6
p-tolyl 5-O-p-methoxybenzyl-1-thio-2,3-O-xylylene-α-D-arabinofuranoside

: C₆₅H₇₇N₃O₁₃

: 8-azidooctyl 5-O-p-methoxybenzyl-2,3-O-xylylene-β-D-arabinofuranosyl-(1→2)-3,5-di-O-benzyl-α-D-arabinofuranosyl-(1→5)-2,3-di-O-benzyl-α-D-arabinofuranosyl-(1→5)-2,3-di-O-benzyl-α-D-arabinofuranoside

Guidance literature:: p-tolyl 5-O-p-methoxybenzyl-1-thio-2,3-O-xylylene-α-D-arabinofuranoside; C₆₅H₇₇N₃O₁₃; In dichloromethane; for 1h; Molecular sieve; Inert atmosphere;

With N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -60 - -40 ℃; for 1h; Molecular sieve; Inert atmosphere;
DOI:10.1021/acs.joc.8b00410

Reference yield: 65.0%

: 1239914-71-6
p-tolyl 5-O-p-methoxybenzyl-1-thio-2,3-O-xylylene-α-D-arabinofuranoside

: 402759-09-5
methyl 3,5-di-O-benzyl-α-D-arabinofuranosyl-(1->3)-[3,5-di-O-benzyl-α-D-arabinofuranosyl-(1->5)]-2-O-benzyl-α-D-arabinofuranoside

: 1239914-91-0
methyl 5-O-p-methoxybenzyl-2,3-O-xylylene-β-D-arabinofuranosyl-(1->2)-3,5-di-O-benzyl-α-D-arabinofuranosyl-(1->3)-[5-O-p-methoxybenzyl-2,3-O-xylylene-β-D-arabinofuranosyl-(1->2)-3,5-di-O-benzyl-α-D-arabinofuranosyl-(1->5)]-2-O-benzyl-α-D-arabinofuranoside

Guidance literature:: p-tolyl 5-O-p-methoxybenzyl-1-thio-2,3-O-xylylene-α-D-arabinofuranoside; methyl 3,5-di-O-benzyl-α-D-arabinofuranosyl-(1->3)-[3,5-di-O-benzyl-α-D-arabinofuranosyl-(1->5)]-2-O-benzyl-α-D-arabinofuranoside; In dichloromethane; at 20 ℃; for 1h; Molecular sieve; Inert atmosphere;

With N-iodo-succinimide; silver trifluoromethanesulfonate; In dichloromethane; at -45 ℃; for 0.75h; stereoselective reaction; Inert atmosphere;
DOI:10.1021/ol101520q