hexa(4-bromophenyl)disiloxane

Base Information

• Chemical Name: hexa(4-bromophenyl)disiloxane
• CAS No.: 16576-77-5
• Molecular Formula: C₃₆H₂₄Br₆OSi₂
• Molecular Weight: 1008.18
• Mol file: 16576-77-5.mol

Synonyms:hexa(4-bromophenyl)disiloxane

Chemical Property of hexa(4-bromophenyl)disiloxane

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of hexa(4-bromophenyl)disiloxane

There total 2 articles about hexa(4-bromophenyl)disiloxane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

tris(4-bromophenyl)silane (18373-69-8) → hexa(4-bromophenyl)disiloxane (16576-77-5)

Guidance literature:

With indium(III) bromide; sodium hydroxide; In tetrahydrofuran; water; at 20 ℃; for 12h;

DOI:10.1039/c7cc06022j

Reference yield:

→ hexa(4-bromophenyl)disiloxane (16576-77-5)

Guidance literature:

Bis(tri-p-bromphenyl-silyl)-oxalat, Δ auf 172grad;

DOI:10.1002/zaac.19673520108

Reference yield: 79.0%

carbon dioxide (124-38-9,18923-20-1) + hexa(4-bromophenyl)disiloxane (16576-77-5) → hexakis(4-carboxyphenyl)-disiloxane

Guidance literature:

hexa(4-bromophenyl)disiloxane; With n-butyllithium; In tetrahydrofuran; at -70 ℃; for 1.5h; Inert atmosphere;

carbon dioxide; In tetrahydrofuran; at 20 ℃; Inert atmosphere;

DOI:10.1039/c7cc06022j

upstream raw materials:

tris(4-bromophenyl)silane