5-((16S,17S)-16-methoxy-17-methylpentatriacontane-1-sulfonyl)-1-phenyl-1H-triazole

Base Information

Chemical Name:5-((16S,17S)-16-methoxy-17-methylpentatriacontane-1-sulfonyl)-1-phenyl-1H-triazole
CAS No.:934502-97-3
Molecular Formula:C₄₄H₈₀N₄O₃S
Molecular Weight:745.21
Hs Code.:

Synonyms:5-((16S,17S)-16-methoxy-17-methylpentatriacontane-1-sulfonyl)-1-phenyl-1H-triazole

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Chemical Property of 5-((16S,17S)-16-methoxy-17-methylpentatriacontane-1-sulfonyl)-1-phenyl-1H-triazole

Chemical Property:

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Technology Process of 5-((16S,17S)-16-methoxy-17-methylpentatriacontane-1-sulfonyl)-1-phenyl-1H-triazole

There total 24 articles about 5-((16S,17S)-16-methoxy-17-methylpentatriacontane-1-sulfonyl)-1-phenyl-1H-triazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 934503-48-7
5-((16S,17S)-16-methoxy-17-methylpentatriacontyl-1-sulfanyl)-1-phenyl-1H-tetrazole

: 934502-97-3
5-((16S,17S)-16-methoxy-17-methylpentatriacontane-1-sulfonyl)-1-phenyl-1H-triazole

Guidance literature:: With ammonium molybdate tetrahydrate; dihydrogen peroxide; In tetrahydrofuran; at 20 ℃; for 1h;
DOI:10.1016/j.tet.2007.01.007

Reference yield:

: 934502-76-8
(S)-3-((R)-2,2-dimethyl[1,3]dioxolan-4-yl)butyric acid methyl ester

: 934502-97-3
5-((16S,17S)-16-methoxy-17-methylpentatriacontane-1-sulfonyl)-1-phenyl-1H-triazole

Guidance literature:: Multi-step reaction with 16 steps

1.1: 80 percent / lithium aluminium hydride / tetrahydrofuran / 1 h / Heating

2.1: 81 percent / pyridinium chlorochromate / CH₂Cl₂ / 0.5 h / Heating

3.1: 93 percent / lithium hexamethyldisilazide / tetrahydrofuran / 16 h / 20 °C

4.1: 88 percent / hydrogen / palladium on charcoal / ethanol; methanol

5.1: 97 percent / p-toluenesulfonic acid monohydrate / tetrahydrofuran; methanol; H₂O / 4.5 h / Heating

6.1: 92 percent / aq. sodium hydroxide; cetrimide; p-toluenesulfonyl chloride / CH₂Cl₂ / 0.5 h

7.1: magnesium / tetrahydrofuran / 2 h / Heating

7.2: 64 percent / copper iodide / tetrahydrofuran / 3 h / -30 °C

8.1: 100 percent / sodium hydride / tetrahydrofuran; various solvent(s) / 16 h / 20 °C

9.1: 95 percent / p-toluenesulfonic acid monohydrate / tetrahydrofuran; methanol; H₂O / 0.5 h / Heating

10.1: 83 percent / pyridinium chlorochromate / CH₂Cl₂ / 0.75 h / Heating

11.1: 87 percent / lithium hexamethyldisilazide / tetrahydrofuran / 16 h / 20 °C

12.1: 100 percent / hydrogen / palladium on charcoal / ethanol

13.1: 95 percent / potassium hydroxide / methanol; tetrahydrofuran / 3 h / 40 °C

14.1: 76 percent / N-bromosuccinimide; triphenylphosphine / CH₂Cl₂ / 1 h / 0 °C

15.1: 99 percent / potassium carbonate / acetone / 18 h / 20 - 40 °C

16.1: 91 percent / ammonium heptamolybdate(VI) tetrahydrate; aq. hydrogen peroxide / tetrahydrofuran; various solvent(s) / 1 h / 20 °C

With potassium hydroxide; sodium hydroxide; N-Bromosuccinimide; lithium aluminium tetrahydride; ammonium molybdate tetrahydrate; hydrogen; dihydrogen peroxide; cetyltrimethylammonim bromide; sodium hydride; potassium carbonate; toluene-4-sulfonic acid; magnesium; p-toluenesulfonyl chloride; triphenylphosphine; pyridinium chlorochromate; lithium hexamethyldisilazane; palladium on activated charcoal; In tetrahydrofuran; methanol; ethanol; dichloromethane; water; acetone; 3.1: Julia-Kocienski reaction / 11.1: Julia-Kocienski reaction;
DOI:10.1016/j.tet.2007.01.007

Reference yield:

: 934502-77-9
(S)-3-((R)-2,2-dimethyl[1,3]dioxolan-4-yl)butan-1-ol

: 934502-97-3
5-((16S,17S)-16-methoxy-17-methylpentatriacontane-1-sulfonyl)-1-phenyl-1H-triazole

Guidance literature:: Multi-step reaction with 15 steps

1.1: 81 percent / pyridinium chlorochromate / CH₂Cl₂ / 0.5 h / Heating

2.1: 93 percent / lithium hexamethyldisilazide / tetrahydrofuran / 16 h / 20 °C

3.1: 88 percent / hydrogen / palladium on charcoal / ethanol; methanol

4.1: 97 percent / p-toluenesulfonic acid monohydrate / tetrahydrofuran; methanol; H₂O / 4.5 h / Heating

5.1: 92 percent / aq. sodium hydroxide; cetrimide; p-toluenesulfonyl chloride / CH₂Cl₂ / 0.5 h

6.1: magnesium / tetrahydrofuran / 2 h / Heating

6.2: 64 percent / copper iodide / tetrahydrofuran / 3 h / -30 °C

7.1: 100 percent / sodium hydride / tetrahydrofuran; various solvent(s) / 16 h / 20 °C

8.1: 95 percent / p-toluenesulfonic acid monohydrate / tetrahydrofuran; methanol; H₂O / 0.5 h / Heating

9.1: 83 percent / pyridinium chlorochromate / CH₂Cl₂ / 0.75 h / Heating

10.1: 87 percent / lithium hexamethyldisilazide / tetrahydrofuran / 16 h / 20 °C

11.1: 100 percent / hydrogen / palladium on charcoal / ethanol

12.1: 95 percent / potassium hydroxide / methanol; tetrahydrofuran / 3 h / 40 °C

13.1: 76 percent / N-bromosuccinimide; triphenylphosphine / CH₂Cl₂ / 1 h / 0 °C

14.1: 99 percent / potassium carbonate / acetone / 18 h / 20 - 40 °C

15.1: 91 percent / ammonium heptamolybdate(VI) tetrahydrate; aq. hydrogen peroxide / tetrahydrofuran; various solvent(s) / 1 h / 20 °C

With potassium hydroxide; sodium hydroxide; N-Bromosuccinimide; ammonium molybdate tetrahydrate; hydrogen; dihydrogen peroxide; cetyltrimethylammonim bromide; sodium hydride; potassium carbonate; toluene-4-sulfonic acid; magnesium; p-toluenesulfonyl chloride; triphenylphosphine; pyridinium chlorochromate; lithium hexamethyldisilazane; palladium on activated charcoal; In tetrahydrofuran; methanol; ethanol; dichloromethane; water; acetone; 2.1: Julia-Kocienski reaction / 10.1: Julia-Kocienski reaction;
DOI:10.1016/j.tet.2007.01.007