[NiCl₂(N,N-bis(dicyclohexylphosphinomethyl)methylamine)]

Base Information

• Chemical Name: [NiCl₂(N,N-bis(dicyclohexylphosphinomethyl)methylamine)]
• CAS No.: 1161882-47-8
• Molecular Formula: C₂₇H₅₁Cl₂NNiP₂
• Molecular Weight: 581.252
• Mol file: 1161882-47-8.mol

Synonyms:[NiCl₂(N,N-bis(dicyclohexylphosphinomethyl)methylamine)]

Chemical Property of [NiCl₂(N,N-bis(dicyclohexylphosphinomethyl)methylamine)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [NiCl₂(N,N-bis(dicyclohexylphosphinomethyl)methylamine)]

There total 1 articles about [NiCl₂(N,N-bis(dicyclohexylphosphinomethyl)methylamine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

nickel(II) chloride hexahydrate + N,N-bis(dicyclohexylphosphinomethyl)methylamine (163353-91-1) → [NiCl2(N,N-bis(dicyclohexylphosphinomethyl)methylamine)] (1161882-47-8)

Guidance literature:

In not given; (N2), Schlenk technique; treatment of Ni-salt with phosphine;

DOI:10.1080/15533170802255351

Reference yield: 93.6%

1,5-pentanedioic acid (110-94-1) + [NiCl2(N,N-bis(dicyclohexylphosphinomethyl)methylamine)] (1161882-47-8) → [(N,N-bis(dicyclohexylphosphinomethyl)Ni(succinate)]

Guidance literature:

With silver(l) oxide; In dichloromethane; (N2), Schlenk technique; Ag2O added to stirred sol. of Ni-complex, succinic acid added, mixt. refluxed for 8 h; mixt. cooled, filtered (Celite), evapd., product precipitated with diethyl ether, filtered, dried; elem. anal.;

DOI:10.1080/15533170802255351

Reference yield: 80.0%

Glutamic acid (617-65-2,21675-62-7,23009-64-5,25104-13-6,84960-48-5,25513-46-6) + [NiCl2(N,N-bis(dicyclohexylphosphinomethyl)methylamine)] (1161882-47-8) → [(N,N-bis(dicyclohexylphosphinomethyl)methylamine)Ni(glutamate)]

Guidance literature:

With silver(l) oxide; In dichloromethane; byproducts: AgCl; (N2), Schlenk technique; to stirred soln. of Ni-complex Ag2O, then acid added, refluxed for 8 h; evapd., filtered through Celite, pptd. with diethyl ether, filtered, dried; elem. anal.;

DOI:10.1080/15533170802293238

upstream raw materials:

N,N-bis(dicyclohexylphosphinomethyl)methylamine

Downstream raw materials:

[(N,N-bis(dicyclohexylphosphinomethyl)methylamine)Ni(carbonate)]

[(N,N-bis(dicyclohexylphosphinomethyl)methylamine)Ni(salicylate)]

Refernces

• 1、 Serindag, Osman,Keles, Mustafa. "Synthesis of some nickel(II) diphosphine complexes having coordinated carboxylates". . p. 445 - 447. Retrieved 2009/02/06.