[Pt(C₆H₄CH₃)(C₆H₃(CH₂N(CH₃)2)2-o,o')]

Base Information

• Chemical Name: [Pt(C₆H₄CH₃)(C₆H₃(CH₂N(CH₃)2)2-o,o')]
• CAS No.: 95532-50-6
• Molecular Formula: C₁₉H₂₆N₂Pt
• Molecular Weight: 477.509
• Mol file: 95532-50-6.mol

Synonyms:[Pt(C₆H₄CH₃)(C₆H₃(CH₂N(CH₃)2)2-o,o')]

Chemical Property of [Pt(C₆H₄CH₃)(C₆H₃(CH₂N(CH₃)2)2-o,o')]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pt(C₆H₄CH₃)(C₆H₃(CH₂N(CH₃)2)2-o,o')]

There total 1 articles about [Pt(C₆H₄CH₃)(C₆H₃(CH₂N(CH₃)2)2-o,o')] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

[2,6-bis(dimethylaminomethyl)-1-phenyl]platinium bromide + (2-methylphenyl)lithium (6699-93-0) → {Pt(2-tolyl)(C6H3(CH2NMe2)2-2,6)} (95532-50-6)

Guidance literature:

In diethyl ether; byproducts: LiBr; (N2), soln. of the Li-compd. added to a suspn. of the complex in ether at 223 K, stirred at room temp. for 20 min; pptn. filtered off, washed with cold pentane, extd. with benzene, extract concd., pentane added, recrystd. from CH2Cl2/pentane, elem. anal.;

DOI:10.1016/0022-328X(86)80460-0

Reference yield: 82.0%

[Pt(C6H4CH3)(C6H3(CH2N(CH3)2)2-o,o')] (95532-50-6) → [Pt(o-tolyl)(C6H3(CH3)(CH2N(CH3)2)2-o,o')]I (95532-53-9)

Guidance literature:

With CH₃I; In acetone; excess of freshly distilled MeI; stirred for 2 h; evapn. of the resulting suspn. to dryness followed by washing the residue with diethyl ether and benzene; recrystn. from CH2Cl2/pentane; elem. anal.;

DOI:10.1021/ja00296a010

Reference yield:

{Pt(2-tolyl)(C6H3(CH2NMe2)2-2,6)} (95532-50-6) → cis-{Pt(2-tolyl)I2(C6H3(CH2NMe2)2-2,6)} (125542-11-2)

Guidance literature:

With iodine; In benzene; not isolated; detn. by comparisation of (1)H-NMR spectra;

upstream raw materials:

(2-methylphenyl)lithium

Downstream raw materials:

cis-{Pt(2-tolyl)I₂(C₆H₃(CH₂NMe₂)2-2,6)}

[Pt(o-tolyl)(C₆H₃(CH₃)(CH₂N(CH₃)2)2-o,o')]I