2-methyl-3-phenyl-3-triethylarsonio-2-silapropane-2-thiolate

Base Information

• Chemical Name: 2-methyl-3-phenyl-3-triethylarsonio-2-silapropane-2-thiolate
• CAS No.: 466637-53-6
• Molecular Formula: C₁₅H₂₇AsSSi
• Molecular Weight: 342.452
• Mol file: 466637-53-6.mol

Synonyms:2-methyl-3-phenyl-3-triethylarsonio-2-silapropane-2-thiolate

Chemical Property of 2-methyl-3-phenyl-3-triethylarsonio-2-silapropane-2-thiolate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 2-methyl-3-phenyl-3-triethylarsonio-2-silapropane-2-thiolate

There total 2 articles about 2-methyl-3-phenyl-3-triethylarsonio-2-silapropane-2-thiolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.8%

hexamethylcyclotrisilathiane (3574-04-7) + benzylidene-triethyl-λ5-arsane → 2-methyl-3-phenyl-3-triethylarsonio-2-silapropane-2-thiolate (466637-53-6)

Guidance literature:

In tetrahydrofuran; at 15 ℃; for 12h;

DOI:10.1023/A:1015828520503

Reference yield:

Triethylbenzylarsonium bromide (62882-58-0) → 2-methyl-3-phenyl-3-triethylarsonio-2-silapropane-2-thiolate (466637-53-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 82.3 percent / NaN(SiMe₃)2 / tetrahydrofuran / 0.17 h / Heating

2: 45.8 percent / tetrahydrofuran / 12 h / 15 °C

With sodium hexamethyldisilazane; In tetrahydrofuran;

DOI:10.1023/A:1015828520503

Reference yield:

2-methyl-3-phenyl-3-triethylarsonio-2-silapropane-2-thiolate (466637-53-6) → triethylarsine (617-75-4) + stilbene (588-59-0) + 2,2,4,4-tetramethyl-5-phenyl-2,4-disila-1,3-dithiolane

Guidance literature:

In perdeuteriopyridine; at 40 - 50 ℃; for 12h; Title compound not separated from byproducts; Irradiation;

DOI:10.1023/A:1015828520503

upstream raw materials:

hexamethylcyclotrisilathiane

Triethylbenzylarsonium bromide

Downstream raw materials:

triethylarsine

stilbene