(2S,3S,4R)-5-<(tert-Butyldiphenylsilyl)oxy>-3-methoxy-2,4-dimethyl-1-pentanol

Base Information

Chemical Name:(2S,3S,4R)-5-<(tert-Butyldiphenylsilyl)oxy>-3-methoxy-2,4-dimethyl-1-pentanol
CAS No.:172603-12-2
Molecular Formula:C₂₄H₃₆O₃Si
Molecular Weight:400.634
Hs Code.:

Synonyms:(2S,3S,4R)-5-<(tert-Butyldiphenylsilyl)oxy>-3-methoxy-2,4-dimethyl-1-pentanol

Suppliers and Price of (2S,3S,4R)-5-<(tert-Butyldiphenylsilyl)oxy>-3-methoxy-2,4-dimethyl-1-pentanol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (2S,3S,4R)-5-<(tert-Butyldiphenylsilyl)oxy>-3-methoxy-2,4-dimethyl-1-pentanol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (2S,3S,4R)-5-<(tert-Butyldiphenylsilyl)oxy>-3-methoxy-2,4-dimethyl-1-pentanol

There total 4 articles about (2S,3S,4R)-5-<(tert-Butyldiphenylsilyl)oxy>-3-methoxy-2,4-dimethyl-1-pentanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 172603-11-1
(2R,3S,4R)-1-(Benzyloxy)-5-<(tert-butyldiphenylsilyl)oxy>-3-methoxy-2,4-dimethylpentane

: 172603-12-2
(2S,3S,4R)-5-<(tert-Butyldiphenylsilyl)oxy>-3-methoxy-2,4-dimethyl-1-pentanol

Guidance literature:: With hydrogen; palladium dichloride; In methanol; for 0.333333h;
DOI:10.1021/jo00128a032

Reference yield:

: 108393-28-8
(2S,3R,4S)-5-benzyloxy-2,3-dimethylpentane-1,4-diol

: 172603-12-2
(2S,3S,4R)-5-<(tert-Butyldiphenylsilyl)oxy>-3-methoxy-2,4-dimethyl-1-pentanol

Guidance literature:: Multi-step reaction with 3 steps

1: imidazole / dimethylformamide / 14 h / 25 °C

2: NaH / dimethylformamide / 1.) 0 deg C, 30 min, 2.) 25 deg C, 1 h

3: 86 percent / H₂ / PdCl₂ / methanol / 0.33 h

With 1H-imidazole; hydrogen; sodium hydride; palladium dichloride; In methanol; N,N-dimethyl-formamide;
DOI:10.1021/jo00128a032

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 172603-12-2
(2S,3S,4R)-5-<(tert-Butyldiphenylsilyl)oxy>-3-methoxy-2,4-dimethyl-1-pentanol

Guidance literature:: Multi-step reaction with 3 steps

1: imidazole / dimethylformamide / 14 h / 25 °C

2: NaH / dimethylformamide / 1.) 0 deg C, 30 min, 2.) 25 deg C, 1 h

3: 86 percent / H₂ / PdCl₂ / methanol / 0.33 h

With 1H-imidazole; hydrogen; sodium hydride; palladium dichloride; In methanol; N,N-dimethyl-formamide;
DOI:10.1021/jo00128a032