Acetic acid 3-acetyl-6-benzenesulfonyl-5-methoxy-7-methyl-1,2,3,6-tetrahydro-pyrrolo[3,2-e]indol-4-yl ester

Base Information

Chemical Name:Acetic acid 3-acetyl-6-benzenesulfonyl-5-methoxy-7-methyl-1,2,3,6-tetrahydro-pyrrolo[3,2-e]indol-4-yl ester
CAS No.:100671-51-0
Molecular Formula:C₂₂H₂₂N₂O₆S
Molecular Weight:442.492
Hs Code.:

Synonyms:Acetic acid 3-acetyl-6-benzenesulfonyl-5-methoxy-7-methyl-1,2,3,6-tetrahydro-pyrrolo[3,2-e]indol-4-yl ester

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Chemical Property of Acetic acid 3-acetyl-6-benzenesulfonyl-5-methoxy-7-methyl-1,2,3,6-tetrahydro-pyrrolo[3,2-e]indol-4-yl ester

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Technology Process of Acetic acid 3-acetyl-6-benzenesulfonyl-5-methoxy-7-methyl-1,2,3,6-tetrahydro-pyrrolo[3,2-e]indol-4-yl ester

There total 10 articles about Acetic acid 3-acetyl-6-benzenesulfonyl-5-methoxy-7-methyl-1,2,3,6-tetrahydro-pyrrolo[3,2-e]indol-4-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 100671-47-4
tert-butyl 3,6-dihydro-4-((dimethoxyphosphinyl)oxy)-5-hydroxy-7-methyl-6-(phenylsulfonyl)benzo<1,2-b:4,3-b'>dipyrrole-1-carboxylate

: 100671-51-0
Acetic acid 3-acetyl-6-benzenesulfonyl-5-methoxy-7-methyl-1,2,3,6-tetrahydro-pyrrolo[3,2-e]indol-4-yl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 50 percent / tetrahydrofuran / 15 h / 20 °C

2: 1.)NaOMe / 1.) MeOH, 3 h, 25 deg C

3: trifluoroacetic acid / CHCl₃ / 1 h / 20 °C

4: 80 percent / triethylamine / toluene / 6 h / 110 °C

5: 1.) triethylsilane / 1.) trifluoroacetic acid, 20 deg C, 1 h

With triethylsilane; sodium methylate; triethylamine; trifluoroacetic acid; In tetrahydrofuran; chloroform; toluene;
DOI:10.1021/ja00243a026

Reference yield:

: 100671-45-2
tert-butyl 3,4,5,6-tetrahydro-6-(phenylsulfonyl)-4,5-dioxobenzo<1,2-b:4,3-b'>dipyrrole-7-carboxylate

: 100671-51-0
Acetic acid 3-acetyl-6-benzenesulfonyl-5-methoxy-7-methyl-1,2,3,6-tetrahydro-pyrrolo[3,2-e]indol-4-yl ester

Guidance literature:: Multi-step reaction with 7 steps

1: 300 mg / benzene / 2 h / 80 °C

2: 75 percent / tetrahydrofuran; H₂O / 1 h / 20 °C

3: 50 percent / tetrahydrofuran / 15 h / 20 °C

4: 1.)NaOMe / 1.) MeOH, 3 h, 25 deg C

5: trifluoroacetic acid / CHCl₃ / 1 h / 20 °C

6: 80 percent / triethylamine / toluene / 6 h / 110 °C

7: 1.) triethylsilane / 1.) trifluoroacetic acid, 20 deg C, 1 h

With triethylsilane; sodium methylate; triethylamine; trifluoroacetic acid; In tetrahydrofuran; chloroform; water; toluene; benzene;
DOI:10.1021/ja00243a026

Reference yield:

: 100693-24-1
4-Acetoxy-6-benzenesulfonyl-5-methoxy-7-methyl-3,6-dihydro-pyrrolo[3,2-e]indole-1-carboxylic acid

: 100671-51-0
Acetic acid 3-acetyl-6-benzenesulfonyl-5-methoxy-7-methyl-1,2,3,6-tetrahydro-pyrrolo[3,2-e]indol-4-yl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / triethylamine / toluene / 6 h / 110 °C

2: 1.) triethylsilane / 1.) trifluoroacetic acid, 20 deg C, 1 h

With triethylsilane; triethylamine; In toluene;
DOI:10.1021/ja00243a026