oxiranylmethyl-carbamic acid phenyl ester

Base Information

• Chemical Name: oxiranylmethyl-carbamic acid phenyl ester
• CAS No.: 474671-01-7
• Molecular Formula: C₁₀H₁₁NO₃
• Molecular Weight: 193.202
• Mol file: 474671-01-7.mol

Synonyms:oxiranylmethyl-carbamic acid phenyl ester

Chemical Property of oxiranylmethyl-carbamic acid phenyl ester

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of oxiranylmethyl-carbamic acid phenyl ester

There total 1 articles about oxiranylmethyl-carbamic acid phenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

phenyl N-(2-propenyl)carbamate (40580-72-1) → oxiranylmethyl-carbamic acid phenyl ester (474671-01-7)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 4 - 20 ℃; for 60h;

DOI:10.1021/jo026287v

Reference yield: 67.0%

di-tert-butyl dicarbonate (24424-99-5) + oxiranylmethyl-carbamic acid phenyl ester (474671-01-7) → C15H19NO5 (474670-51-4)

Guidance literature:

With dmap; triethylamine; In tetrahydrofuran; at 20 ℃; for 18h;

DOI:10.1021/jo026287v

Reference yield:

oxiranylmethyl-carbamic acid phenyl ester (474671-01-7) → C20H29NO5Si

Guidance literature:

Multi-step reaction with 2 steps

1.1: 67 percent / triethylamine; 4-(dimethylamino)pyridine / tetrahydrofuran / 18 h / 20 °C

2.1: n-butyllithium / tetrahydrofuran; hexane / 0.25 h / -78 °C

2.2: boron trifluoride etherate / tetrahydrofuran; hexane / 2.5 h / -78 °C

With dmap; n-butyllithium; triethylamine; In tetrahydrofuran; hexane;

DOI:10.1021/jo026287v

upstream raw materials:

phenyl N-(2-propenyl)carbamate

Downstream raw materials:

C₁₅H₁₉NO₅