Technology Process of 1,1,1-(CO)3-2-Ph-closo-1,2,3,4-MnC3B7H9
There total 4 articles about 1,1,1-(CO)3-2-Ph-closo-1,2,3,4-MnC3B7H9 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
1,2-dimethoxyethane; dichloromethane;
byproducts: LiBF4, C10H8; (N2 or Ar); a soln. of Li salt in glyme added dropwise to a suspn. of Mncomplex in CH2Cl2, stirred for 2 h at room temp.; exposed to air and filtered (silica gel), the silica gel washed (Et2O), the filtrate evapd. (vac.), dissolved in n-pentane, chromd. (silica gel,pentane), evapd. (vac.), recrystd. (n-pentane, -78°C);
DOI:10.1021/ja062201u
- Guidance literature:
-
In
1,2-dimethoxyethane;
byproducts: LiBr, CO; (N2 or Ar); a soln. of B compd. added dropwise to a soln. of Mn complex,stirred for 12 h at room temp.; exposed to air and filtered (silica gel), the silica gel washed (Et2O), the filtrate evapd. (vac.), dissolved in n-pentane, chromd. (silica gel,pentane), evapd. (vac.), recrystd. (n-pentane, -78°C); elem. ana l.;
DOI:10.1021/ja062201u
- Guidance literature:
-
In
neat (no solvent, solid phase);
byproducts: CNC(CH3)3; a soln. of Mn complex evapd. (vac.), dried in vac. overnight;
DOI:10.1021/ja062201u
![[(η-6-naphthalene) tricarbonyl manganese] BF4](/Databaselist/images/loading.webp)
