tricarbonyl[N-(η6-2-methoxybenzylidene)diphenylphosphinamide]chromium

Base Information

• Chemical Name: tricarbonyl[N-(η6-2-methoxybenzylidene)diphenylphosphinamide]chromium
• CAS No.: 260548-01-4
• Molecular Formula: C₂₃H₁₈CrNO₅P
• Molecular Weight: 471.369
• Mol file: 260548-01-4.mol

Synonyms:tricarbonyl[N-(η6-2-methoxybenzylidene)diphenylphosphinamide]chromium

Chemical Property of tricarbonyl[N-(η6-2-methoxybenzylidene)diphenylphosphinamide]chromium

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of tricarbonyl[N-(η6-2-methoxybenzylidene)diphenylphosphinamide]chromium

There total 1 articles about tricarbonyl[N-(η6-2-methoxybenzylidene)diphenylphosphinamide]chromium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

tricarbonyl(η6-2-methoxybenzaldehyde)chromium(0) (36249-94-2,12181-92-9,71327-35-0) + diphenylphosphinamide (5994-87-6) → tricarbonyl[N-(η6-2-methoxybenzylidene)diphenylphosphinamide]chromium (260548-01-4)

Guidance literature:

With TiCl₄; (C₂H₅)3N; In dichloromethane; (N2, exclusion of sunlight); triethylamine added dropwise (stirring); cooled to 0°C; TiCl4 slowly added; 4 h; filtered over Celite; washed (30 ml, satd. NaHCO3); extd. (CH2Cl2); solvent evapd.; flash column chromy. (AcOEt:Et3N, 10:1);

DOI:10.1016/S0022-328X(99)00601-4

upstream raw materials:

tricarbonyl(η⁶-2-methoxybenzaldehyde)chromium(0)

diphenylphosphinamide