methyl 6-C-(2,6-anhydro-4,5,7-tri-O-benzyl-1,3-dideoxy-D-arabino-hept-2-enit-1-yl)-2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-pyranoside

Base Information

Chemical Name:methyl 6-C-(2,6-anhydro-4,5,7-tri-O-benzyl-1,3-dideoxy-D-arabino-hept-2-enit-1-yl)-2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-pyranoside
CAS No.:232603-20-2
Molecular Formula:C₅₆H₆₀O₉
Molecular Weight:877.087
Hs Code.:

Synonyms:methyl 6-C-(2,6-anhydro-4,5,7-tri-O-benzyl-1,3-dideoxy-D-arabino-hept-2-enit-1-yl)-2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-pyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 6-C-(2,6-anhydro-4,5,7-tri-O-benzyl-1,3-dideoxy-D-arabino-hept-2-enit-1-yl)-2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-pyranoside

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of methyl 6-C-(2,6-anhydro-4,5,7-tri-O-benzyl-1,3-dideoxy-D-arabino-hept-2-enit-1-yl)-2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-pyranoside

There total 9 articles about methyl 6-C-(2,6-anhydro-4,5,7-tri-O-benzyl-1,3-dideoxy-D-arabino-hept-2-enit-1-yl)-2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-pyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 1241951-06-3
C₅₆H₅₆O₉

: 232603-20-2
methyl 6-C-(2,6-anhydro-4,5,7-tri-O-benzyl-1,3-dideoxy-D-arabino-hept-2-enit-1-yl)-2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-pyranoside

Guidance literature:: With hydrogen; In tetrahydrofuran; methanol; at 20 ℃; under 750.075 Torr;
DOI:10.1021/ol101625p

Reference yield: 68.0%

: 232603-16-6
(2R,3R,4S,5R,6S)-3,4,5-Tris-benzyloxy-2-[3-((1R,2S,3R)-2,3-bis-benzyloxy-1-benzyloxymethyl-pent-4-enyloxy)-but-3-enyl]-6-methoxy-tetrahydro-pyran

: 232603-20-2
methyl 6-C-(2,6-anhydro-4,5,7-tri-O-benzyl-1,3-dideoxy-D-arabino-hept-2-enit-1-yl)-2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-pyranoside

Guidance literature:: <(F3C)2MeCO>2Mo=N(2,6-iPr2Ph)(=CHCMe2Ph); In toluene; at 60 ℃; glove box;
DOI:10.1016/S0040-4039(99)00815-1

Reference yield:

: 232603-12-2
3,4,6-tri-O-benzyl-1,2-dideoxy-D-arabino-hex-1-enyl (methyl 2,3,4-tri-O-benzyl-6,7-dideoxy-α-D-gluco-octopyranosid)uronate

: 232603-20-2
methyl 6-C-(2,6-anhydro-4,5,7-tri-O-benzyl-1,3-dideoxy-D-arabino-hept-2-enit-1-yl)-2,3,4-tri-O-benzyl-6-deoxy-α-D-gluco-pyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: TiCl₄; Zn; TMEDA / PbCl₂ / CH₂Cl₂; tetrahydrofuran / 1 h / 60 °C

2: 68 percent / (N,N'-Mes₂-imidazolidin-2-yl)Ru=CHPh(PCy₃)Cl₂ / toluene / 3 h / 60 °C

With N,N,N,N,-tetramethylethylenediamine; titanium tetrachloride; zinc; tri(cycloxexyl)phosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene][benzylidene]ruthenium(IV) dichloride; lead(II) chloride; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1021/jo030039x