N'-(2,4-dinitrophenyl)-2-methylpropanehydrazide

Base Information

• Chemical Name: N'-(2,4-dinitrophenyl)-2-methylpropanehydrazide
• CAS No.: 7461-93-0
• Molecular Formula: C₁₀H₁₂N₄O₅
• Molecular Weight: 268.229
• NSC Number: 404129
• DSSTox Substance ID: DTXSID80400862
• Wikidata: Q82203915
• Mol file: 7461-93-0.mol

Synonyms:7461-93-0;NSC404129;N'-(2,4-dinitrophenyl)-2-methylpropanehydrazide;DTXSID80400862;NSC-404129;Isobutyric acid, 2(2,4-dinitrophenyl) hydrazide

Chemical Property of N'-(2,4-dinitrophenyl)-2-methylpropanehydrazide

Chemical Property:

• Boiling Point: 379.4°Cat760mmHg
• Flash Point: 183.3°C
• Density: 1.423g/cm³
• XLogP3: 2.8
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 3
• Exact Mass: 268.08076950
• Heavy Atom Count: 19
• Complexity: 362

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)C(=O)NNC1=C(C=C(C=C1)[N+](=O)[O-])[N+](=O)[O-]

Technology Process of N'-(2,4-dinitrophenyl)-2-methylpropanehydrazide

There total 3 articles about N'-(2,4-dinitrophenyl)-2-methylpropanehydrazide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-Methyl-propion-2.4-dinitro-phenyl-hydrazon-saeurebromid (14947-24-1) → 2-methyl-propanoic acid, 2-(2,4-dinitrophenyl)hydrazide (7461-93-0)

Guidance literature:

With water; In acetone;

DOI:10.1021/jo01266a055

Reference yield:

isobutyraldehyde-((E)-2,4-dinitro-phenylhydrazone) (74335-78-7) → 2-methyl-propanoic acid, 2-(2,4-dinitrophenyl)hydrazide (7461-93-0)

Guidance literature:

Multi-step reaction with 2 steps

1: Br₂ / aq. acetic acid / 20 °C

2: H₂O / acetone

With water; bromine; In acetic acid; acetone;

DOI:10.1021/jo01266a055

Reference yield:

→ 2-methyl-propanoic acid, 2-(2,4-dinitrophenyl)hydrazide (7461-93-0)

Guidance literature:

entspr. Ester, 1. N2H2, 2. F-DNP;

DOI:10.1042/bj1110401

upstream raw materials:

2-Methyl-propion-2.4-dinitro-phenyl-hydrazon-saeurebromid

isobutyraldehyde-((E)-2,4-dinitro-phenylhydrazone)

Refernces