diphenylmethyl <(p-methoxyphenyl)sulfonyl>methyl sulfoxide

Base Information

• Chemical Name: diphenylmethyl <(p-methoxyphenyl)sulfonyl>methyl sulfoxide
• CAS No.: 132102-78-4
• Molecular Formula: C₂₁H₂₀O₄S₂
• Molecular Weight: 400.519
• Mol file: 132102-78-4.mol

Synonyms:diphenylmethyl <(p-methoxyphenyl)sulfonyl>methyl sulfoxide

Chemical Property of diphenylmethyl <(p-methoxyphenyl)sulfonyl>methyl sulfoxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diphenylmethyl <(p-methoxyphenyl)sulfonyl>methyl sulfoxide

There total 4 articles about diphenylmethyl <(p-methoxyphenyl)sulfonyl>methyl sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

diphenylmethyl <(p-methoxyphenyl)sulfonyl>methyl sulfide (132102-84-2) → diphenylmethyl <(p-methoxyphenyl)sulfonyl>methyl sulfoxide (132102-78-4)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In chloroform; for 2h; Ambient temperature;

DOI:10.1021/jo00004a017

Reference yield:

p-anisyl methyl sulfone (3517-90-6) → diphenylmethyl <(p-methoxyphenyl)sulfonyl>methyl sulfoxide (132102-78-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 1) BuLi / 1) THF, -77 deg C, 0.5 h, 2) THF, -77 deg C, 0.5 h

2: 80 percent / m-chloroperoxybenzoic acid / CHCl₃ / 2 h / Ambient temperature

With n-butyllithium; 3-chloro-benzenecarboperoxoic acid; In chloroform;

DOI:10.1021/jo00004a017

Reference yield:

sodium 4-methoxybenzenesulfinate (6462-50-6) → diphenylmethyl <(p-methoxyphenyl)sulfonyl>methyl sulfoxide (132102-78-4)

Guidance literature:

Multi-step reaction with 3 steps

1: 61 percent / dimethylsulfoxide / Ambient temperature

2: 1) BuLi / 1) THF, -77 deg C, 0.5 h, 2) THF, -77 deg C, 0.5 h

3: 80 percent / m-chloroperoxybenzoic acid / CHCl₃ / 2 h / Ambient temperature

With n-butyllithium; 3-chloro-benzenecarboperoxoic acid; In chloroform; dimethyl sulfoxide;

DOI:10.1021/jo00004a017

upstream raw materials:

diphenylmethyl <(p-methoxyphenyl)sulfonyl>methyl sulfide

p-anisyl methyl sulfone

sodium 4-methoxybenzenesulfinate

diphenylmethyl p-toluenethiosulfonate

Downstream raw materials:

thiobenzophenone S-oxide

p-anisyl methyl sulfone